Compounds
| ID | Spectrum Quality | Annotated Name |
|---|
COMPOUND NPA015394
PROPERTIES
| NPAID | NPA015394 |
|---|---|
| CLUSTER ID | 819 |
| NODE ID | 711 |
| NAME | Oximidine II |
| FORMULA | C23H24N2O6 |
| MOLECULAR WEIGHT (Da) | 424.4530 |
| ACCURATE MASS (Da) | 424.1634 |
| ORIGIN ORGANISM TYPE | Bacterium |
| ORIGIN GENUS | Pseudomonas |
| ORIGIN SPECIES | sp. Q52002 |
| InChIKey | CUJVFMQWSZPITL-OOQAZEOOSA-N |
| InChI | InChI=1S/C23H24N2O6/c1-30-25-16-8-14-21(28)24-15-7-13-20-18(26)11-5-3-2-4-9-17-10-6-12-19(27)22(17)23(29)31-20/h2-14,16,18,20,26-27H,15H2,1H3,(H,24,28)/b3-2-,9-4+,11-5-,13-7+,14-8-,25-16-/t18-,20-/m0/s1 |
| SMILES | CO/N=C\C=C/C(=O)NC/C=C/[C@H]1[C@H](/C=C\C=C/C=C/C2=C(C(=CC=C2)O)C(=O)O1)O |
ORIGINAL ISOLATION REFERENCE
| CITATION | Kim, Jin Woo; Shin-Ya, Kazuo; Furihata, Kazuo; Hayakawa, Yoichi; Seto, Haruo Oximidines I and II: Novel antitumor macrolides from Pseudomonas sp Journal of Organic Chemistry 1999 64 (1) 153-155. | ||
|---|---|---|---|
| DOI | 10.1021/jo9814997 | PMID | 11674097 |
SYNTHESES
| CITATION 1 | Wang X; Porco JA Total synthesis of the salicylate enamide macrolide oximidine II. Journal of the American Chemical Society 2003 125 (20) 6040-6041. DOI: 10.1021/ja034030o PMID: 12785818 | ||
|---|---|---|---|
| CITATION 2 | Molander GA; Dehmel F Formal total synthesis of oximidine II via a Suzuki-type cross-coupling macrocyclization employing potassium organotrifluoroborates. Journal of the American Chemical Society 2004 126 (33) 10313-10318. DOI: 10.1021/ja047190o PMID: 15315445 | ||
