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Compounds

COMPOUND NPA000137

STRUCTURE
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EXTERNAL LINKS
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PROPERTIES
NPAID NPA000137
CLUSTER ID 116
NODE ID 110
NAME VM-55599
FORMULA C25H35N3O
MOLECULAR WEIGHT (Da) 393.5750
ACCURATE MASS (Da) 393.2780
ORIGIN ORGANISM TYPE Fungus
ORIGIN GENUS Penicillium
ORIGIN SPECIES sp. strain, IMI 332995
InChIKey NESVIABHQZBIFX-IYHWZCMTSA-N
InChI InChI=1S/C25H35N3O/c1-21(2)11-12-28-15-24-13-17-16-9-7-8-10-18(16)26-19(17)22(3,4)23(24,5)14-25(21,28)20(29)27(24)6/h7-10,17,19,26H,11-15H2,1-6H3/t17?,19?,23-,24-,25+/m1/s1
SMILES CN1C(=O)[C@]23C[C@]4(C)C(C)(C)C5NC6=CC=CC=C6C5C[C@]14CN2CCC3(C)C
ORIGINAL ISOLATION REFERENCE
CITATION Blanchflower, S E; Banks, R M; Everett, J R; Reading, C Further novel metabolites of the paraherquamide family. Journal of Antibiotics 1993 46 (9) 1355-1363.
DOI 10.7164/antibiotics.46.1355 PMID 8226314
ORIGINAL ISOLATION TAXONOMY
RANK NAME DB LINK NCBI
Domain Eukarya - 2759
Kingdom Fungi MycoBank 4751
Phylum Ascomycota MycoBank 4890
Class Eurotiomycetes MycoBank 147545
Order Eurotiales MycoBank 5042
Family Aspergillaceae MycoBank 1131492
Genus Penicillium MycoBank 5073
REVISIONS
VERSION SMILES CITATION
Original Isolation C[C@@H]1CCN2[C@]13C[C@@H]4[C@](C2)(CC5=C(C4(C)C)NC6=CC=CC=C56)NC3=O Blanchflower, S E; Banks, R M; Everett, J R; Reading, C Further novel metabolites of the paraherquamide family. Journal of Antibiotics 1993 46 (9) 1355-1363. DOI: 10.7164/antibiotics.46.1355 PMID: 8226314
2 CN1C(=O)[C@]23C[C@]4(C)C(C)(C)C5NC6=CC=CC=C6C5C[C@]14CN2CCC3(C)C Sanz-Cervera, Juan F; Williams, Robert M Asymmetric total synthesis of (-)-VM55599: establishment of the absolute stereochemistry and biogenetic implications. Journal of the American Chemical Society 2002 124 (11) 2556-9. DOI: 10.1021/ja017425l PMID: 11890806
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