{"id":33906,"npaid":"NPA033906","original_name":"Motobamide","mol_formula":"C63H95N11O10S","mol_weight":"1198.5870","exact_mass":"1197.6984","inchikey":"KGAZEHXLNKMYBU-PGTWJRKASA-N","smiles":"CSCC[C@@H]1NC(=O)[C@@H]2CCCN2C(=O)[C@H](C(C)C)NC(=O)[C@@H]2CCCN2C(=O)[C@@H]2CCCN2C(=O)[C@H](CC(C)C)NC(=O)[C@@H]2C[C@@]3(CC=C(C)C)C4=CC=CC=C4N[C@H]3N2C(=O)[C@@H]2CCCN2C(=O)[C@H](C(C)C)NC(=O)[C@H](CC(C)C)NC1=O","cluster_id":26,"node_id":25,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C63H95N11O10S/c1-35(2)24-26-63-34-49-56(79)66-44(33-37(5)6)57(80)72-29-16-22-47(72)58(81)70-27-14-21-46(70)55(78)69-51(39(9)10)60(83)71-28-15-20-45(71)54(77)64-42(25-31-85-11)52(75)65-43(32-36(3)4)53(76)68-50(38(7)8)61(84)73-30-17-23-48(73)59(82)74(49)62(63)67-41-19-13-12-18-40(41)63/h12-13,18-19,24,36-39,42-51,62,67H,14-17,20-23,25-34H2,1-11H3,(H,64,77)(H,65,75)(H,66,79)(H,68,76)(H,69,78)/t42-,43-,44-,45-,46-,47-,48-,49-,50-,51-,62-,63-/m0/s1","m_plus_h":"1198.7057","m_plus_na":"1220.6876","origin_reference":{"doi":"10.1021/acs.jnatprod.1c00234","pmid":33983736,"authors":"Takahashi, Hiroki; Iwasaki, Arihiro; Kurisawa, Naoaki; Suzuki, Ryota; Jeelani, Ghulam; Matsubara, Teruhiko; Sato, Toshinori; Nozaki, Tomoyoshi; Suenaga, Kiyotake","title":"Motobamide, an Antitrypanosomal Cyclic Peptide from a Leptolyngbya sp. Marine Cyanobacterium.","journal":"Journal of Natural Products","year":2021,"volume":"84","issue":"5","pages":"1649-1655"},"origin_organism":{"id":913,"type":"Bacterium","genus":"Leptolyngbya","species":"sp.","taxon":{"id":459,"name":"Leptolyngbya","rank":"genus","taxon_db":"lpsn","external_id":"0","ncbi_id":47251,"ancestors":[{"id":1,"name":"Bacteria","rank":"domain","taxon_db":"lpsn","external_id":"0","ncbi_id":2},{"id":417,"name":"Cyanobacteria","rank":"phylum","taxon_db":"lpsn","external_id":"0","ncbi_id":1117},{"id":418,"name":"Cyanophyceae","rank":"class","taxon_db":"lpsn","external_id":"0","ncbi_id":null},{"id":449,"name":"Synechococcales","rank":"order","taxon_db":"lpsn","external_id":"0","ncbi_id":1890424},{"id":458,"name":"Leptolyngbyaceae","rank":"family","taxon_db":"lpsn","external_id":"0","ncbi_id":1890438}]}},"syntheses":[],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.1021/acs.jnatprod.1c00234","structure_smiles":"CSCC[C@@H]1NC(=O)[C@@H]2CCCN2C(=O)[C@H](C(C)C)NC(=O)[C@@H]2CCCN2C(=O)[C@@H]2CCCN2C(=O)[C@H](CC(C)C)NC(=O)[C@@H]2C[C@@]3(CC=C(C)C)C4=CC=CC=C4N[C@H]3N2C(=O)[C@@H]2CCCN2C(=O)[C@H](C(C)C)NC(=O)[C@H](CC(C)C)NC1=O","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0001813","name":"Peptidomimetics","chemont_id":"CHEMONTID:0001813","description":"Compounds containing non-peptidic structural elements that is capable of mimicking or antagonizing the biological action(s) of a natural parent peptide."},"smiles":"CSCC[C@@H]1NC(=O)[C@@H]2CCCN2C(=O)[C@@H](NC(=O)[C@@H]2CCCN2C(=O)[C@@H]2CCCN2C(=O)[C@H](CC(C)C)NC(=O)[C@@H]2C[C@]3(CC=C(C)C)[C@@H](NC4=CC=CC=C34)N2C(=O)[C@@H]2CCCN2C(=O)[C@@H](NC(=O)[C@H](CC(C)C)NC1=O)C(C)C)C(C)C","kingdom":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000000","name":"Organic compounds","chemont_id":"CHEMONTID:0000000","description":"Compounds that contain at least one carbon atom, excluding isocyanide/cyanide and their non-hydrocarbyl derivatives, thiophosgene, carbon diselenide, carbon monosulfide, carbon disulfide, carbon subsulfide, carbon monoxide, carbon dioxide, Carbon suboxide, and dicarbon monoxide."},"inchikey":"InChIKey=KGAZEHXLNKMYBU-PGTWJRKASA-N","subclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0002010","name":"Hybrid peptides","chemont_id":"CHEMONTID:0002010","description":"Compounds containing at least two different types of amino acids (alpha, beta, gamma, delta) linked to each other through a peptide bond."},"ancestors":["Alpha amino acid amides","Alpha amino acids and derivatives","Amines","Amino acids and derivatives","Amino acids, peptides, and analogues","Azacyclic compounds","Benzenoids","Carboxylic acid amides","Carboxylic acid derivatives","Carboxylic acids and derivatives","Chemical entities","Dialkylamines","Dialkylthioethers","Fatty Acyls","Fatty amides","Hybrid peptides","Hydrocarbon derivatives","Indoles","Indoles and derivatives","Indolines","Lactams","Leucine and derivatives","Lipids and lipid-like molecules","Methionine and derivatives","N-acyl amines","N-acyl-alpha amino acids and derivatives","N-acylpyrrolidines","Organic acids and derivatives","Organic compounds","Organic nitrogen compounds","Organic oxides","Organic oxygen compounds","Organoheterocyclic compounds","Organonitrogen compounds","Organooxygen compounds","Organopnictogen compounds","Organosulfur compounds","Peptidomimetics","Pyrroles","Pyrrolidine carboxylic acids and derivatives","Pyrrolidinecarboxamides","Pyrrolidines","Pyrroloindoles","Secondary alkylarylamines","Secondary amines","Sulfenyl compounds","Tertiary carboxylic acid amides","Thioethers","Valine and derivatives"],"superclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000264","name":"Organic acids and derivatives","chemont_id":"CHEMONTID:0000264","description":"Compounds an organic acid or a derivative thereof."},"description":"This compound belongs to the class of organic compounds known as hybrid peptides. 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