{"id":33347,"npaid":"NPA033347","original_name":"Myxarylin","mol_formula":"C22H29N5O5","mol_weight":"443.5040","exact_mass":"443.2169","inchikey":"YNCKCZXUTZJZTQ-ULQDDVLXSA-N","smiles":"CN[C@H]1CC2=CC=C(O)C(=C2)N2C=NC=C2C[C@@H](C(=O)O)NC(=O)[C@H](CC(C)C)NC1=O","cluster_id":9599,"node_id":6420,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C22H29N5O5/c1-12(2)6-16-21(30)26-17(22(31)32)9-14-10-24-11-27(14)18-8-13(4-5-19(18)28)7-15(23-3)20(29)25-16/h4-5,8,10-12,15-17,23,28H,6-7,9H2,1-3H3,(H,25,29)(H,26,30)(H,31,32)/t15-,16-,17-/m0/s1","m_plus_h":"444.2242","m_plus_na":"466.2061","origin_reference":{"doi":"10.3390/molecules26247483","pmid":34946566,"authors":"Šenica, Petra; Frank, Nicolas A.; Hug, Joachim J.; Müller, Rolf; Panter, Fabian; Walt, Christine","title":"Genome-guided discovery of the first myxobacterial biarylitide myxarylin reveals distinct c–n biaryl crosslinking in ripp biosynthesis","journal":"Molecules","year":2021,"volume":"26","issue":"24","pages":"None"},"origin_organism":{"id":10779,"type":"Bacterium","genus":"Pyxidicoccus","species":"fallax An d48","taxon":{"id":186,"name":"Pyxidicoccus","rank":"genus","taxon_db":"lpsn","external_id":"517556","ncbi_id":224458,"ancestors":[{"id":1,"name":"Bacteria","rank":"domain","taxon_db":"lpsn","external_id":"0","ncbi_id":2},{"id":2,"name":"Proteobacteria","rank":"phylum","taxon_db":"lpsn","external_id":"0","ncbi_id":1224},{"id":168,"name":"Deltaproteobacteria","rank":"class","taxon_db":"lpsn","external_id":"0","ncbi_id":28221},{"id":169,"name":"Myxococcales","rank":"order","taxon_db":"lpsn","external_id":"0","ncbi_id":29},{"id":183,"name":"Myxococcaceae","rank":"family","taxon_db":"lpsn","external_id":"0","ncbi_id":31}]}},"syntheses":[],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.3390/molecules26247483","structure_smiles":"CN[C@H]1CC2=CC=C(O)C(=C2)N2C=NC=C2C[C@@H](C(=O)O)NC(=O)[C@H](CC(C)C)NC1=O","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0003298","name":"Polypeptides","chemont_id":"CHEMONTID:0003298","description":"Peptides containing ten or more amino acid residues."},"smiles":"CN[C@H]1CC2=CC=C(O)C(=C2)N2C=NC=C2C[C@H](NC(=O)[C@H](CC(C)C)NC1=O)C(O)=O","kingdom":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000000","name":"Organic compounds","chemont_id":"CHEMONTID:0000000","description":"Compounds that contain at least one carbon atom, excluding isocyanide/cyanide and their non-hydrocarbyl derivatives, thiophosgene, carbon diselenide, carbon monosulfide, carbon disulfide, carbon subsulfide, carbon monoxide, carbon dioxide, Carbon suboxide, and dicarbon monoxide."},"inchikey":"InChIKey=YNCKCZXUTZJZTQ-ULQDDVLXSA-N","subclass":null,"ancestors":["1-hydroxy-2-unsubstituted benzenoids","Alpha amino acid amides","Alpha amino acids and derivatives","Amidines","Amines","Amino acids","Amino acids and derivatives","Amino acids, peptides, and analogues","Azacyclic compounds","Azoles","Benzenoids","Carboximidamides","Carboxylic acid amides","Carboxylic acid derivatives","Carboxylic acids","Carboxylic acids and derivatives","Chemical entities","Cyclic peptides","Dialkylamines","Fatty Acyls","Fatty amides","Formamidines","Heteroaromatic compounds","Hydrocarbon derivatives","Imidazoles","Lactams","Leucine and derivatives","Lipids and lipid-like molecules","Monocarboxylic acids and derivatives","N-acyl amines","N-acyl-L-alpha-amino acids","N-acyl-alpha amino acids","N-acyl-alpha amino acids and derivatives","Organic 1,3-dipolar compounds","Organic Polymers","Organic acids and derivatives","Organic compounds","Organic nitrogen compounds","Organic oxides","Organic oxygen compounds","Organoheterocyclic compounds","Organonitrogen compounds","Organooxygen compounds","Organopnictogen compounds","Peptides","Phenols","Phenylimidazoles","Polypeptides","Propargyl-type 1,3-dipolar organic compounds","Secondary amines","Substituted imidazoles"],"superclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0003297","name":"Organic Polymers","chemont_id":"CHEMONTID:0003297","description":"Organic compounds, generally large molecules or macromolecules, which are composed of many repeating units."},"description":"This compound belongs to the class of organic compounds known as polypeptides. 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