{"id":33097,"npaid":"NPA033097","original_name":"Hexacosalactone A","mol_formula":"C45H65NO11","mol_weight":"796.0110","exact_mass":"795.4558","inchikey":"XLVNGASIPGZSDP-XXPFVUKHSA-N","smiles":"CO[C@@H]1C[C@H](O)[C@@H](C)[C@H](O)[C@@H](C)C[C@@H](C)C(=O)C[C@H](C(C)C)OC(=O)/C(C)=C/C=C/C(C)=C/C=C/C(C)=C\\C[C@H](OC(=O)/C=C/C(=O)NC2=C(O)CCC2=O)[C@@H]1C","cluster_id":9546,"node_id":6391,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C45H65NO11/c1-26(2)39-24-36(49)30(6)23-31(7)44(53)32(8)37(50)25-40(55-10)33(9)38(56-42(52)22-21-41(51)46-43-34(47)18-19-35(43)48)20-17-28(4)14-11-13-27(3)15-12-16-29(5)45(54)57-39/h11-17,21-22,26,30-33,37-40,44,47,50,53H,18-20,23-25H2,1-10H3,(H,46,51)/b14-11+,15-12+,22-21+,27-13+,28-17-,29-16+/t30-,31+,32-,33+,37+,38+,39-,40-,44-/m1/s1","m_plus_h":"796.4631","m_plus_na":"818.4450","origin_reference":{"doi":"10.1021/acs.jnatprod.1c00144","pmid":34170140,"authors":"Shi, Peng; Li, Yaoyao; Zhu, Jing; Shen, Yuemao; Wang, Haoxin","title":"Targeted Discovery of the Polyene Macrolide Hexacosalactone A from Streptomyces by Reporter-Guided Selection of Fermentation Media.","journal":"Journal of Natural Products","year":2021,"volume":"84","issue":"7","pages":"1924-1929"},"origin_organism":{"id":693,"type":"Bacterium","genus":"Streptomyces","species":"sp. 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They have the generic structure RC(=O)C(R')=C, R = organyl group and R'= any heteroatom."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0003889","name":"Vinylogous acids","chemont_id":"CHEMONTID:0003889","description":"Organic compounds containing a hydroxyl group, which is indirectly attached to a carbonyl via an intervening vinyl (>C=C<) moiety."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0001363","name":"Enones","chemont_id":"CHEMONTID:0001363","description":"Compounds containing the enone functional group, with the structure RC(=O)CR'."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0003626","name":"Enoate esters","chemont_id":"CHEMONTID:0003626","description":"An alpha,beta-unsaturated carboxylic ester of general formula R1C(R2)=C(R3)C(=O)OR4 (R4= organyl compound) in which the ester C=O function is conjugated to a C=C double bond at the alpha,beta position."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000275","name":"Acryloyl compounds","chemont_id":"CHEMONTID:0000275","description":"Organic compounds containing the acryloyl functional group (which has the core fragment but-3-en-2-one)."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0001661","name":"Secondary alcohols","chemont_id":"CHEMONTID:0001661","description":"Compounds containing a secondary alcohol functional group, with the general structure HOC(R)(R') (R,R'=alkyl, aryl)."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000050","name":"Lactones","chemont_id":"CHEMONTID:0000050","description":"Cyclic esters of hydroxy carboxylic acids, containing a 1-oxacycloalkan-2-one structure, or analogues having unsaturation or heteroatoms replacing one or more carbon atoms of the ring."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0003487","name":"Cyclic ketones","chemont_id":"CHEMONTID:0003487","description":"Organic compounds containing a ketone that is conjugated to a cyclic moiety."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0004140","name":"Oxacyclic compounds","chemont_id":"CHEMONTID:0004140","description":"Organic compounds containing an heterocycle with at least one oxygen atom linked to a ring carbon."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0001167","name":"Dialkyl ethers","chemont_id":"CHEMONTID:0001167","description":"Organic compounds containing the dialkyl ether functional group, with the formula ROR', where R and R' are alkyl groups."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000475","name":"Carboxylic acid amides","chemont_id":"CHEMONTID:0000475","description":"Carboxylic acid derivatives containing a carbonyl group in which the carbon atom is linked to a nitrogen atom (substituted or not). 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