{"id":29430,"npaid":"NPA029430","original_name":"Clifednamide G","mol_formula":"C29H34N2O7","mol_weight":"522.5980","exact_mass":"522.2366","inchikey":"FHKOBILSYIITHS-LMPYDYSBSA-N","smiles":"CC(=O)[C@H]1[C@@H]2C=C[C@H](/C=C/C=C/C(N)=O)[C@H](/C=C/C=C/C(O)=C3C(=O)N[C@@H](CCC(=O)O)C3=O)[C@H]2C[C@H]1C","cluster_id":8677,"node_id":5863,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C29H34N2O7/c1-16-15-21-19(18(7-3-6-10-24(30)34)11-12-20(21)26(16)17(2)32)8-4-5-9-23(33)27-28(37)22(31-29(27)38)13-14-25(35)36/h3-12,16,18-22,26,33H,13-15H2,1-2H3,(H2,30,34)(H,31,38)(H,35,36)/b7-3+,8-4+,9-5+,10-6+,27-23?/t16-,18+,19+,20-,21-,22+,26+/m1/s1","m_plus_h":"523.2439","m_plus_na":"545.2258","origin_reference":{"doi":"10.1021/acs.jnatprod.0c00900","pmid":32915576,"authors":"Jiao, Yu-Jie; Li, Yao-Yao; Liu, Yan; Shen, Yue-Mao; Wang, Hao-Xin; Zhu, De-Yu","title":"Expression of the Clifednamide Biosynthetic Pathway in Streptomyces Generates 27,28- seco-Derivatives","journal":"Journal of Natural Products","year":2020,"volume":"83","issue":"9","pages":"2803-2808"},"origin_organism":{"id":10074,"type":"Bacterium","genus":"Streptomyces","species":"sp. 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Ketones that have one or more alpha-hydrogen atoms undergo keto-enol tautomerization, the tautomer being an enol."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0001205","name":"Carboxylic acids","chemont_id":"CHEMONTID:0001205","description":"Compounds containing a carboxylic acid group with the formula -C(=O)OH."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0004139","name":"Azacyclic compounds","chemont_id":"CHEMONTID:0004139","description":"Organic compounds containing an heterocycle with at least one nitrogen atom and one carbon atom linked to each other."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0004557","name":"Organopnictogen compounds","chemont_id":"CHEMONTID:0004557","description":"Compounds containing a bond between carbon a pnictogen atom. 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