{"id":28479,"npaid":"NPA028479","original_name":"KK-1","mol_formula":"C56H89N9O14","mol_weight":"1112.3770","exact_mass":"1111.6529","inchikey":"DIYFOMLSLDLOMV-UHFFFAOYSA-N","smiles":"CCC(C)C1C(=O)NCC(=O)N(C)C(C(C)C)C(=O)NC(CC2=CC=C(OC)C=C2)C(=O)OC(C)C(=O)N2CCCCC2C(=O)N(C)C(C(C)C)C(=O)NC(C(C)C)C(=O)N(C)C(CC(=O)O)C(=O)N(C)C(C(C)C)C(=O)N1C","cluster_id":142,"node_id":135,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C56H89N9O14/c1-18-34(10)47-48(69)57-29-41(66)61(13)44(31(4)5)49(70)58-38(27-36-22-24-37(78-17)25-23-36)56(77)79-35(11)51(72)65-26-20-19-21-39(65)52(73)62(14)45(32(6)7)50(71)59-43(30(2)3)54(75)60(12)40(28-42(67)68)53(74)63(15)46(33(8)9)55(76)64(47)16/h22-25,30-35,38-40,43-47H,18-21,26-29H2,1-17H3,(H,57,69)(H,58,70)(H,59,71)(H,67,68)","m_plus_h":"1112.6602","m_plus_na":"1134.6421","origin_reference":{"doi":"10.3389/fmicb.2018.00690","pmid":29686660,"authors":"Yoshimi A; Yamaguchi S; Fujioka T; Kawai K; Gomi K; Machida M; Abe K","title":"Heterologous Production of a Novel Cyclic Peptide Compound, KK-1, in Aspergillus oryzae.","journal":"Frontiers in Microbiology","year":2018,"volume":"9","issue":null,"pages":"690"},"origin_organism":{"id":9908,"type":"Fungus","genus":"Curvularia","species":"clavata","taxon":{"id":652,"name":"Curvularia","rank":"genus","taxon_db":"mycobank","external_id":"7847","ncbi_id":5502,"ancestors":[{"id":599,"name":"Eukarya","rank":"domain","taxon_db":"mycobank","external_id":"0","ncbi_id":2759},{"id":600,"name":"Fungi","rank":"kingdom","taxon_db":"mycobank","external_id":"90157","ncbi_id":4751},{"id":617,"name":"Ascomycota","rank":"phylum","taxon_db":"mycobank","external_id":"90031","ncbi_id":4890},{"id":618,"name":"Dothideomycetes","rank":"class","taxon_db":"mycobank","external_id":"501481","ncbi_id":147541},{"id":645,"name":"Pleosporales","rank":"order","taxon_db":"mycobank","external_id":"90563","ncbi_id":92860},{"id":648,"name":"Pleosporaceae","rank":"family","taxon_db":"mycobank","external_id":"81188","ncbi_id":28556}]}},"syntheses":[],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.3389/fmicb.2018.00690","structure_smiles":"CCC(C)C1C(=O)NCC(=O)N(C)C(C(C)C)C(=O)NC(CC2=CC=C(OC)C=C2)C(=O)OC(C)C(=O)N2CCCCC2C(=O)N(C)C(C(C)C)C(=O)NC(C(C)C)C(=O)N(C)C(CC(=O)O)C(=O)N(C)C(C(C)C)C(=O)N1C","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"mibig","external_db_code":"BGC0001636"},{"external_db_name":"npmrd","external_db_code":"NP0017964"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0001813","name":"Peptidomimetics","chemont_id":"CHEMONTID:0001813","description":"Compounds 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