{"id":26721,"npaid":"NPA026721","original_name":"Minnamide A","mol_formula":"C74H132N10O18","mol_weight":"1449.9220","exact_mass":"1448.9721","inchikey":"QGFKIJHYWFMMLE-KPZCQLIWSA-N","smiles":"CCC[C@@H](O)C[C@H](C)C[C@@H](O)C[C@H](C)C[C@@H](O)C[C@H](C)C[C@H](O)CC(=O)N[C@@H](CC(C)C)C(=O)N(C)[C@@H](C(=O)N[C@H](CO)C(=O)N[C@H](CC(C)C)C(=O)N(C)[C@H](C(=O)N[C@@H](CO)C(=O)N(C)[C@H](C(=O)N(C)[C@@H](CCC(N)=O)C(=O)N[C@H](CO)CC1=CC=C(OC)C=C1)C(C)C)C(C)C)[C@@H](C)CC","cluster_id":8074,"node_id":546,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C74H132N10O18/c1-20-22-52(88)31-46(11)32-53(89)33-47(12)34-54(90)35-48(13)36-55(91)38-63(93)77-57(29-42(3)4)71(98)84(18)66(49(14)21-2)70(97)79-59(40-86)67(94)78-58(30-43(5)6)72(99)82(16)64(44(7)8)69(96)80-60(41-87)73(100)83(17)65(45(9)10)74(101)81(15)61(27-28-62(75)92)68(95)76-51(39-85)37-50-23-25-56(102-19)26-24-50/h23-26,42-49,51-55,57-61,64-66,85-91H,20-22,27-41H2,1-19H3,(H2,75,92)(H,76,95)(H,77,93)(H,78,94)(H,79,97)(H,80,96)/t46-,47-,48-,49-,51-,52+,53+,54+,55-,57-,58+,59+,60-,61-,64-,65-,66+/m0/s1","m_plus_h":"1449.9794","m_plus_na":"1471.9613","origin_reference":{"doi":"10.1021/acs.orglett.9b00135","pmid":30730753,"authors":"Sumimoto, Shimpei; Kobayashi, Masayuki; Sato, Rio; Shinomiya, Seiichi; Iwasaki, Arihiro; Suda, Shoichiro; Teruya, Toshiaki; Inuzuka, Toshiyasu; Ohno, Osamu; Suenaga, Kiyotake","title":"Minnamide A, a Linear Lipopeptide from the Marine Cyanobacterium Okeania hirsuta","journal":"Organic Letters","year":2019,"volume":"21","issue":"4","pages":"1187-1190"},"origin_organism":{"id":8779,"type":"Bacterium","genus":"Okeania","species":"hirsuta","taxon":{"id":480,"name":"Okeania","rank":"genus","taxon_db":"lpsn","external_id":"0","ncbi_id":1458928,"ancestors":[{"id":1,"name":"Bacteria","rank":"domain","taxon_db":"lpsn","external_id":"0","ncbi_id":2},{"id":417,"name":"Cyanobacteria","rank":"phylum","taxon_db":"lpsn","external_id":"0","ncbi_id":1117},{"id":418,"name":"Cyanophyceae","rank":"class","taxon_db":"lpsn","external_id":"0","ncbi_id":null},{"id":473,"name":"Oscillatoriales","rank":"order","taxon_db":"lpsn","external_id":"0","ncbi_id":1150},{"id":474,"name":"Oscillatoriaceae","rank":"family","taxon_db":"lpsn","external_id":"0","ncbi_id":1892254}]}},"syntheses":[],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.1021/acs.orglett.9b00135","structure_smiles":"CCC[C@@H](O)C[C@H](C)C[C@@H](O)C[C@H](C)C[C@@H](O)C[C@H](C)C[C@H](O)CC(=O)N[C@@H](CC(C)C)C(=O)N(C)[C@@H](C(=O)N[C@H](CO)C(=O)N[C@H](CC(C)C)C(=O)N(C)[C@H](C(=O)N[C@@H](CO)C(=O)N(C)[C@H](C(=O)N(C)[C@@H](CCC(N)=O)C(=O)N[C@H](CO)CC1=CC=C(OC)C=C1)C(C)C)C(C)C)[C@@H](C)CC","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"gnps","external_db_code":"CCMSLIB00004753001%Minnamide A%3"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004753002%Minnamide A%3"},{"external_db_name":"npmrd","external_db_code":"NP0019208"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000265","name":"Carboxylic acids and derivatives","chemont_id":"CHEMONTID:0000265","description":"Compounds containing a carboxylic acid group with the formula -C(=O)OH or a derivative thereof."},"smiles":"[H][C@]([C@@H](C)CC)(N(C)C(=O)[C@H](CC(C)C)NC(=O)C[C@@H](O)C[C@@H](C)C[C@H](O)C[C@@H](C)C[C@H](O)C[C@@H](C)C[C@H](O)CCC)C(=O)N[C@H](CO)C(=O)N[C@H](CC(C)C)C(=O)N(C)[C@@H](C(C)C)C(=O)N[C@@H](CO)C(=O)N(C)[C@@H](C(C)C)C(=O)N(C)[C@@H](CCC(N)=O)C(=O)N[C@H](CO)CC1=CC=C(OC)C=C1","kingdom":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000000","name":"Organic compounds","chemont_id":"CHEMONTID:0000000","description":"Compounds that contain at least one carbon atom, excluding isocyanide/cyanide and their non-hydrocarbyl derivatives, thiophosgene, carbon diselenide, carbon monosulfide, carbon disulfide, carbon subsulfide, carbon monoxide, carbon dioxide, Carbon suboxide, and dicarbon monoxide."},"inchikey":"InChIKey=QGFKIJHYWFMMLE-KPZCQLIWSA-N","subclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000013","name":"Amino acids, peptides, and analogues","chemont_id":"CHEMONTID:0000013","description":"Organic compounds containing an amino acid or a peptide backbone, or derivatives thereof."},"ancestors":["Alcohols and polyols","Alkyl aryl ethers","Alpha amino acid amides","Alpha amino acids and derivatives","Amino acids and derivatives","Amino acids, peptides, and analogues","Amphetamines and derivatives","Anisoles","Benzene and substituted derivatives","Benzenoids","Carbonyl compounds","Carboxylic acid amides","Carboxylic acid derivatives","Carboxylic acids and derivatives","Chemical entities","Diterpenoids","Ethers","Fatty Acyls","Fatty amides","Glutamine and derivatives","Hydrocarbon derivatives","Isoleucine and derivatives","Leucine and derivatives","Lipids and lipid-like molecules","Methoxybenzenes","N-acyl amines","N-acyl-alpha amino acids and derivatives","Oligopeptides","Organic acids and derivatives","Organic compounds","Organic nitrogen compounds","Organic oxides","Organic oxygen compounds","Organonitrogen compounds","Organooxygen compounds","Organopnictogen compounds","Peptides","Phenethylamines","Phenol ethers","Phenoxy compounds","Polyols","Prenol lipids","Primary alcohols","Primary carboxylic acid amides","Secondary alcohols","Secondary carboxylic acid amides","Serine and derivatives","Tertiary carboxylic acid amides","Valine and derivatives"],"superclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000264","name":"Organic acids and derivatives","chemont_id":"CHEMONTID:0000264","description":"Compounds an organic acid or a derivative thereof."},"description":"This compound belongs to the class of organic compounds known as oligopeptides. 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