{"id":17198,"npaid":"NPA017198","original_name":"Cordycepol C","mol_formula":"C15H26O4","mol_weight":"270.3690","exact_mass":"270.1831","inchikey":"CGAGMAHEIWCVNP-XPABHHOTSA-N","smiles":"C[C@H]1CC[C@@H]([C@]12CC[C@@](C=C2)(C)OO)[C@@](C)(CO)O","cluster_id":5810,"node_id":4094,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C15H26O4/c1-11-4-5-12(14(3,17)10-16)15(11)8-6-13(2,19-18)7-9-15/h6,8,11-12,16-18H,4-5,7,9-10H2,1-3H3/t11-,12+,13-,14+,15+/m0/s1","m_plus_h":"271.1904","m_plus_na":"293.1723","origin_reference":{"doi":"10.1002/hlca.201200068","pmid":null,"authors":"Sun, Yisheng; Zhao, Zhao; Feng, Qiangsheng; Xu, Qinqin; Lue, Longxian; Liu, Ji-Kai; Zhang, Ling; Wu, Bin; Li, Yong-Quan","title":"Unusual spirodecane sesquiterpenes and a fumagillol analogue from cordyceps ophioglossoides","journal":"Helvetica Chimica Acta","year":2013,"volume":"96","issue":"1","pages":"76-84"},"origin_organism":{"id":4977,"type":"Fungus","genus":"Cordyceps","species":"ophioglossoides","taxon":{"id":916,"name":"Cordyceps","rank":"genus","taxon_db":"mycobank","external_id":"1240","ncbi_id":45234,"ancestors":[{"id":599,"name":"Eukarya","rank":"domain","taxon_db":"mycobank","external_id":"0","ncbi_id":2759},{"id":600,"name":"Fungi","rank":"kingdom","taxon_db":"mycobank","external_id":"90157","ncbi_id":4751},{"id":617,"name":"Ascomycota","rank":"phylum","taxon_db":"mycobank","external_id":"90031","ncbi_id":4890},{"id":879,"name":"Sordariomycetes","rank":"class","taxon_db":"mycobank","external_id":"90350","ncbi_id":147550},{"id":899,"name":"Hypocreales","rank":"order","taxon_db":"mycobank","external_id":"90477","ncbi_id":5125},{"id":913,"name":"Cordycipitaceae","rank":"family","taxon_db":"mycobank","external_id":"504360","ncbi_id":474943}]}},"syntheses":[],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.1002/hlca.201200068","structure_smiles":"C[C@H]1CC[C@@H]([C@]12CC[C@@](C=C2)(C)OO)[C@@](C)(CO)O","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"npmrd","external_db_code":"NP0323574"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000323","name":"Organooxygen compounds","chemont_id":"CHEMONTID:0000323","description":"Organic compounds containing a bond between a carbon atom and an oxygen atom."},"smiles":"C[C@H]1CC[C@H]([C@](C)(O)CO)[C@]11CC[C@@](C)(OO)C=C1","kingdom":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000000","name":"Organic compounds","chemont_id":"CHEMONTID:0000000","description":"Compounds that contain at least one carbon atom, excluding isocyanide/cyanide and their non-hydrocarbyl derivatives, thiophosgene, carbon diselenide, carbon monosulfide, carbon disulfide, carbon subsulfide, carbon monoxide, carbon dioxide, Carbon suboxide, and dicarbon monoxide."},"inchikey":"InChIKey=CGAGMAHEIWCVNP-XPABHHOTSA-N","subclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000129","name":"Alcohols and polyols","chemont_id":"CHEMONTID:0000129","description":"Organic compounds in which at least one hydroxyl functional group (-OH) is bound to a carbon atom, usually connected to other carbon or hydrogen atoms."},"ancestors":["1,2-diols","Alcohols and polyols","Alkyl hydroperoxides","Chemical entities","Hydrocarbon derivatives","Organic compounds","Organic hydroperoxides","Organic oxygen compounds","Organooxygen compounds","Peroxols","Polyols","Primary alcohols","Tertiary alcohols"],"superclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0004603","name":"Organic oxygen compounds","chemont_id":"CHEMONTID:0004603","description":"Organic compounds that contain one or more oxygen atoms."},"description":"This compound belongs to the class of organic compounds known as tertiary alcohols. 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They have the general formula ROOH, where R is the alkyl group."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000286","name":"Primary alcohols","chemont_id":"CHEMONTID:0000286","description":"Compounds comprising the primary alcohol functional group, with the general structure RCOH (R=alkyl, aryl)."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0004150","name":"Hydrocarbon derivatives","chemont_id":"CHEMONTID:0004150","description":"Derivatives of hydrocarbons obtained by substituting one or more carbon atoms by an heteroatom. They contain at least one carbon atom and heteroatom."}],"molecular_framework":"Aliphatic homopolycyclic compounds","external_descriptors":[],"predicted_chebi_terms":["polyol (CHEBI:26191)","peroxol (CHEBI:35924)","organic molecular entity (CHEBI:50860)","hydroperoxide (CHEBI:35923)","primary alcohol (CHEBI:15734)","organic molecule (CHEBI:72695)","tertiary alcohol (CHEBI:26878)","chemical entity (CHEBI:24431)","oxygen molecular entity (CHEBI:25806)","organooxygen compound (CHEBI:36963)","organic hydroxy compound (CHEBI:33822)","alcohol (CHEBI:30879)","organic peroxide (CHEBI:25702)"],"classification_version":"2.1","predicted_lipidmaps_terms":[]},"npclassifier":{"isglycoside":false,"class_results":["Acorane sesquiterpenoids"],"pathway_results":["Terpenoids"],"superclass_results":["Sesquiterpenoids"]}}