{"id":15915,"npaid":"NPA015915","original_name":"Cremimycin","mol_formula":"C35H53NO9","mol_weight":"631.8070","exact_mass":"631.3720","inchikey":"RUOAKWFUWPYANU-CBSFPUALSA-N","smiles":"CCCCCCC1CC(=O)CCCC(CC(=O)C2=C(C(CC2/C=C(/C=C\\C=C/C(=O)N1)\\C)O[C@H]3C[C@@H]([C@@H]([C@H](O3)C)O)OC)O)O","cluster_id":5498,"node_id":3908,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C35H53NO9/c1-5-6-7-8-13-25-19-26(37)14-11-15-27(38)20-28(39)33-24(17-22(2)12-9-10-16-31(40)36-25)18-30(35(33)42)45-32-21-29(43-4)34(41)23(3)44-32/h9-10,12,16-17,23-25,27,29-30,32,34,38,41-42H,5-8,11,13-15,18-21H2,1-4H3,(H,36,40)/b12-9-,16-10-,22-17+/t23-,24?,25?,27?,29+,30?,32+,34-/m1/s1","m_plus_h":"632.3793","m_plus_na":"654.3612","origin_reference":{"doi":"10.7164/antibiotics.51.123","pmid":9544932,"authors":"Igarashi, Masayuki; Tsuchida, Toshio; Kinoshita, Naoko; Kamijima, Mie; Sawa, Ryuichi; Sawa, Tsutomu; Naganawa, Hiroshi; Hamada, Masa; Takeuchi, Tomio; Yamazaki, Katsuhisa; Ishizuka, Masaaki","title":"Cremimycin, a novel 19-membered macrocyclic lactam antibiotic, from Streptomyces sp","journal":"Journal of Antibiotics","year":1998,"volume":"51","issue":"2","pages":"123-129"},"origin_organism":{"id":5056,"type":"Bacterium","genus":"Streptomyces","species":"sp (MJ635-86F5)","taxon":{"id":283,"name":"Streptomyces","rank":"genus","taxon_db":"lpsn","external_id":"517119","ncbi_id":1883,"ancestors":[{"id":1,"name":"Bacteria","rank":"domain","taxon_db":"lpsn","external_id":"0","ncbi_id":2},{"id":203,"name":"Actinobacteria","rank":"phylum","taxon_db":"lpsn","external_id":"0","ncbi_id":201174},{"id":204,"name":"Actinobacteria","rank":"class","taxon_db":"lpsn","external_id":"0","ncbi_id":null},{"id":275,"name":"Streptomycetales","rank":"order","taxon_db":"lpsn","external_id":"0","ncbi_id":85011},{"id":276,"name":"Streptomycetaceae","rank":"family","taxon_db":"lpsn","external_id":"0","ncbi_id":2062}]}},"syntheses":[],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.7164/antibiotics.51.123","structure_smiles":"CCCCCCC1CC(=O)CCCC(CC(=O)C2=C(C(CC2/C=C(/C=C\\C=C/C(=O)N1)\\C)O[C@H]3C[C@@H]([C@@H]([C@H](O3)C)O)OC)O)O","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"mibig","external_db_code":"BGC0000042"},{"external_db_name":"npmrd","external_db_code":"NP0023654"},{"external_db_name":"npmrd","external_db_code":"NP0268209"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000323","name":"Organooxygen compounds","chemont_id":"CHEMONTID:0000323","description":"Organic compounds containing a bond between a carbon atom and an oxygen atom."},"smiles":"[H]\\C1=C(/[H])\\C(\\C)=C([H])\\C2([H])CC([H])(O[C@@]3([H])C[C@]([H])(OC)[C@]([H])(O)[C@@]([H])(C)O3)C(O)=C2C(=O)CC([H])(O)CCCC(=O)CC([H])(CCCCCC)N=C(O)\\C([H])=C/1\\[H]","kingdom":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000000","name":"Organic compounds","chemont_id":"CHEMONTID:0000000","description":"Compounds that contain at least one carbon atom, excluding isocyanide/cyanide and their non-hydrocarbyl derivatives, thiophosgene, carbon diselenide, carbon monosulfide, carbon disulfide, carbon subsulfide, carbon monoxide, carbon dioxide, Carbon suboxide, and dicarbon monoxide."},"inchikey":"InChIKey=RUOAKWFUWPYANU-CBSFPUALSA-N","subclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000011","name":"Carbohydrates and carbohydrate conjugates","chemont_id":"CHEMONTID:0000011","description":"Monosaccharides, disaccharides, oligosaccharides, polysaccharides, and their derivatives."},"ancestors":["Acetals","Alcohols and polyols","Azacyclic compounds","Carbohydrates and carbohydrate conjugates","Carbonyl compounds","Carboximidic acids","Carboximidic acids and derivatives","Chemical entities","Cyclic carboximidic acids","Cyclic ketones","Dialkyl ethers","Enols","Ethers","Glycosyl compounds","Hexoses","Hydrocarbon derivatives","Ketones","Monosaccharides","O-glycosyl compounds","Organic 1,3-dipolar compounds","Organic acids and derivatives","Organic compounds","Organic nitrogen compounds","Organic oxides","Organic oxygen compounds","Organoheterocyclic compounds","Organonitrogen compounds","Organooxygen compounds","Organopnictogen compounds","Oxacyclic compounds","Oxanes","Polyols","Propargyl-type 1,3-dipolar organic compounds","Secondary alcohols","Vinylogous acids"],"superclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0004603","name":"Organic oxygen compounds","chemont_id":"CHEMONTID:0004603","description":"Organic compounds that contain one or more oxygen atoms."},"description":"This compound belongs to the class of organic compounds known as o-glycosyl compounds. 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