{"id":15714,"npaid":"NPA015714","original_name":"Curvupallide B","mol_formula":"C14H17NO5","mol_weight":"279.2920","exact_mass":"279.1107","inchikey":"MCGMBKWXTCCVNV-CNLWIZLKSA-N","smiles":"C/C=C/C=C/[C@H]1[C@@H]([C@H](C2=C(O1)C(=C)N(C2=O)OC)O)O","cluster_id":2442,"node_id":1917,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C14H17NO5/c1-4-5-6-7-9-11(16)12(17)10-13(20-9)8(2)15(19-3)14(10)18/h4-7,9,11-12,16-17H,2H2,1,3H3/b5-4+,7-6+/t9-,11-,12-/m0/s1","m_plus_h":"280.1180","m_plus_na":"302.0999","origin_reference":{"doi":"10.1016/0040-4020(95)98692-b","pmid":null,"authors":"Abraham, Wolf-Rainer; Meyer, Holger; Abate, Dawit","title":"Curvupallides, a new class of alkaloids from the fungus Curvularia pallescens","journal":"Tetrahedron","year":1995,"volume":"51","issue":"17","pages":"4947-4952"},"origin_organism":{"id":2622,"type":"Fungus","genus":"Curvularia","species":"pallescens","taxon":{"id":652,"name":"Curvularia","rank":"genus","taxon_db":"mycobank","external_id":"7847","ncbi_id":5502,"ancestors":[{"id":599,"name":"Eukarya","rank":"domain","taxon_db":"mycobank","external_id":"0","ncbi_id":2759},{"id":600,"name":"Fungi","rank":"kingdom","taxon_db":"mycobank","external_id":"90157","ncbi_id":4751},{"id":617,"name":"Ascomycota","rank":"phylum","taxon_db":"mycobank","external_id":"90031","ncbi_id":4890},{"id":618,"name":"Dothideomycetes","rank":"class","taxon_db":"mycobank","external_id":"501481","ncbi_id":147541},{"id":645,"name":"Pleosporales","rank":"order","taxon_db":"mycobank","external_id":"90563","ncbi_id":92860},{"id":648,"name":"Pleosporaceae","rank":"family","taxon_db":"mycobank","external_id":"81188","ncbi_id":28556}]}},"syntheses":[],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.1016/0040-4020(95)98692-b","structure_smiles":"C/C=C/C=C/[C@H]1[C@@H]([C@H](C2=C(O1)C(=C)N(C2=O)OC)O)O","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"mibig","external_db_code":"BGC0001563"},{"external_db_name":"npmrd","external_db_code":"NP0325399"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000091","name":"Pyrrolines","chemont_id":"CHEMONTID:0000091","description":"Compounds containing a pyrroline ring, which is a five-member unsaturated aliphatic ring with one nitrogen atom and four carbon atoms."},"smiles":"CON1C(=C)C2=C([C@H](O)[C@@H](O)[C@@H](O2)\\C=C\\C=C\\C)C1=O","kingdom":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000000","name":"Organic compounds","chemont_id":"CHEMONTID:0000000","description":"Compounds that contain at least one carbon atom, excluding isocyanide/cyanide and their non-hydrocarbyl derivatives, thiophosgene, carbon diselenide, carbon monosulfide, carbon disulfide, carbon subsulfide, carbon monoxide, carbon dioxide, Carbon suboxide, and dicarbon monoxide."},"inchikey":"InChIKey=MCGMBKWXTCCVNV-CNLWIZLKSA-N","subclass":null,"ancestors":["1,2-diols","Alcohols and polyols","Azacyclic compounds","Carbonyl compounds","Carboxylic acids and derivatives","Chemical entities","Hydrocarbon derivatives","Organic acids and derivatives","Organic compounds","Organic nitrogen compounds","Organic oxides","Organic oxygen compounds","Organoheterocyclic compounds","Organonitrogen compounds","Organooxygen compounds","Organopnictogen compounds","Oxacyclic compounds","Polyols","Pyrrolines","Secondary alcohols","Vinylogous esters"],"superclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000002","name":"Organoheterocyclic compounds","chemont_id":"CHEMONTID:0000002","description":"Compounds containing a ring with least one carbon atom and one non-carbon atom."},"description":"This compound belongs to the class of organic compounds known as pyrrolines. 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