{"id":14906,"npaid":"NPA014906","original_name":"Alchivemycin B","mol_formula":"C35H53NO9","mol_weight":"631.8070","exact_mass":"631.3720","inchikey":"ODWSFZQNKWSGRM-FATPKMAPSA-N","smiles":"CC=C(C)[C@@H]([C@@H]([C@H]1[C@H]([C@@H]([C@H](CCCC[C@H]2[C@@](O2)([C@H]3C=C[C@H]4C[C@H](C[C@H]([C@H]4[C@@H]3C(=C5C(=O)CN1OC5=O)O)C)C)C)C)O)O)O)O","cluster_id":793,"node_id":688,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C35H53NO9/c1-7-18(3)29(38)32(41)28-33(42)30(39)19(4)10-8-9-11-24-35(6,44-24)22-13-12-21-15-17(2)14-20(5)25(21)26(22)31(40)27-23(37)16-36(28)45-34(27)43/h7,12-13,17,19-22,24-26,28-30,32-33,38-42H,8-11,14-16H2,1-6H3/t17-,19-,20+,21-,22-,24-,25+,26+,28-,29-,30+,32+,33+,35-/m0/s1","m_plus_h":"632.3793","m_plus_na":"654.3612","origin_reference":{"doi":"10.1021/ol401071j","pmid":23819828,"authors":"Kim, Youngju; In, Yasuko; Ishida, Toshimasa; Onaka, Hiroyasu; Igarashi, Yasuhiro","title":"Biosynthetic origin of alchivemycin A, a new polyketide from streptomyces and absolute configuration of alchivemycin B","journal":"Organic Letters","year":2013,"volume":"15","issue":"14","pages":"3514-3517"},"origin_organism":{"id":3898,"type":"Bacterium","genus":"Streptomyces","species":"sp.","taxon":{"id":283,"name":"Streptomyces","rank":"genus","taxon_db":"lpsn","external_id":"517119","ncbi_id":1883,"ancestors":[{"id":1,"name":"Bacteria","rank":"domain","taxon_db":"lpsn","external_id":"0","ncbi_id":2},{"id":203,"name":"Actinobacteria","rank":"phylum","taxon_db":"lpsn","external_id":"0","ncbi_id":201174},{"id":204,"name":"Actinobacteria","rank":"class","taxon_db":"lpsn","external_id":"0","ncbi_id":null},{"id":275,"name":"Streptomycetales","rank":"order","taxon_db":"lpsn","external_id":"0","ncbi_id":85011},{"id":276,"name":"Streptomycetaceae","rank":"family","taxon_db":"lpsn","external_id":"0","ncbi_id":2062}]}},"syntheses":[],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.1021/ol401071j","structure_smiles":"CC=C(C)[C@@H]([C@@H]([C@H]1[C@H]([C@@H]([C@H](CCCC[C@H]2[C@@](O2)([C@H]3C=C[C@H]4C[C@H](C[C@H]([C@H]4[C@@H]3C(=C5C(=O)CN1OC5=O)O)C)C)C)C)O)O)O)O","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"mibig","external_db_code":"BGC0002456"},{"external_db_name":"npmrd","external_db_code":"NP0011895"},{"external_db_name":"npmrd","external_db_code":"NP0171201"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000107","name":"Oxazinanes","chemont_id":"CHEMONTID:0000107","description":"Compounds containing an oxazinane moiety, which consists of a saturated aliphatic six-member ring with one oxygen atom, a nitrogen atom, and four carbon atoms. 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