{"id":12925,"npaid":"NPA012925","original_name":"Showdomycin","mol_formula":"C9H11NO6","mol_weight":"229.1880","exact_mass":"229.0586","inchikey":"FFLUMYXAPXARJP-JBBNEOJLSA-N","smiles":"C1=C(C(=O)NC1=O)[C@H]2[C@@H]([C@@H]([C@H](O2)CO)O)O","cluster_id":4793,"node_id":2135,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C9H11NO6/c11-2-4-6(13)7(14)8(16-4)3-1-5(12)10-9(3)15/h1,4,6-8,11,13-14H,2H2,(H,10,12,15)/t4-,6-,7-,8+/m1/s1","m_plus_h":"230.0659","m_plus_na":"252.0478","origin_reference":{"doi":"10.1073/pnas.57.3.548","pmid":16591497,"authors":"Darnall, K r; Townsend, L b; Robins, R k","title":"The structure of showdomycin, a novel carbon-linked nucleoside antibiotic related to uridine","journal":"Proceedings of the National Academy of Sciences of the United States of America","year":1967,"volume":"57","issue":"3","pages":"548-553"},"origin_organism":{"id":4549,"type":"Bacterium","genus":"Streptomyces","species":"showdoensis","taxon":{"id":283,"name":"Streptomyces","rank":"genus","taxon_db":"lpsn","external_id":"517119","ncbi_id":1883,"ancestors":[{"id":1,"name":"Bacteria","rank":"domain","taxon_db":"lpsn","external_id":"0","ncbi_id":2},{"id":203,"name":"Actinobacteria","rank":"phylum","taxon_db":"lpsn","external_id":"0","ncbi_id":201174},{"id":204,"name":"Actinobacteria","rank":"class","taxon_db":"lpsn","external_id":"0","ncbi_id":null},{"id":275,"name":"Streptomycetales","rank":"order","taxon_db":"lpsn","external_id":"0","ncbi_id":85011},{"id":276,"name":"Streptomycetaceae","rank":"family","taxon_db":"lpsn","external_id":"0","ncbi_id":2062}]}},"syntheses":["10.1021/jo990195x"],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.1073/pnas.57.3.548","structure_smiles":"C1=C(C(=O)NC1=O)[C@H]2[C@@H]([C@@H]([C@H](O2)CO)O)O","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"mibig","external_db_code":"BGC0001778"},{"external_db_name":"npmrd","external_db_code":"NP0006269"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000323","name":"Organooxygen compounds","chemont_id":"CHEMONTID:0000323","description":"Organic compounds containing a bond between a carbon atom and an oxygen atom."},"smiles":"OC[C@H]1O[C@H]([C@H](O)[C@@H]1O)C1=CC(=O)NC1=O","kingdom":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000000","name":"Organic compounds","chemont_id":"CHEMONTID:0000000","description":"Compounds that contain at least one carbon atom, excluding isocyanide/cyanide and their non-hydrocarbyl derivatives, thiophosgene, carbon diselenide, carbon monosulfide, carbon disulfide, carbon subsulfide, carbon monoxide, carbon dioxide, Carbon suboxide, and dicarbon monoxide."},"inchikey":"InChIKey=FFLUMYXAPXARJP-JBBNEOJLSA-N","subclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000011","name":"Carbohydrates and carbohydrate conjugates","chemont_id":"CHEMONTID:0000011","description":"Monosaccharides, disaccharides, oligosaccharides, polysaccharides, and their derivatives."},"ancestors":["Alcohols and polyols","Azacyclic compounds","C-glycosyl compounds","Carbohydrates and carbohydrate conjugates","Carbonyl compounds","Carboxylic acid derivatives","Carboxylic acid imides","Carboxylic acids and derivatives","Chemical entities","Dialkyl ethers","Dicarboximides","Ethers","Glycosyl compounds","Hydrocarbon derivatives","Maleimides","Monosaccharides","N-unsubstituted carboxylic acid imides","Organic acids and derivatives","Organic compounds","Organic nitrogen compounds","Organic oxides","Organic oxygen compounds","Organoheterocyclic compounds","Organonitrogen compounds","Organooxygen compounds","Organopnictogen compounds","Oxacyclic compounds","Pentoses","Primary alcohols","Pyrrolidines","Pyrrolidones","Pyrrolines","Secondary alcohols","Tetrahydrofurans"],"superclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0004603","name":"Organic oxygen compounds","chemont_id":"CHEMONTID:0004603","description":"Organic compounds that contain one or more oxygen atoms."},"description":"This compound belongs to the class of organic compounds known as c-glycosyl compounds. 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