{"id":10945,"npaid":"NPA010945","original_name":"Aphidicolin","mol_formula":"C20H34O4","mol_weight":"338.4880","exact_mass":"338.2457","inchikey":"NOFOAYPPHIUXJR-APNQCZIXSA-N","smiles":"C[C@]12CC[C@H]([C@@]([C@@H]1CC[C@@H]3[C@@]24CC[C@@]([C@H](C3)C4)(CO)O)(C)CO)O","cluster_id":29,"node_id":28,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C20H34O4/c1-17(11-21)15-4-3-13-9-14-10-19(13,7-8-20(14,24)12-22)18(15,2)6-5-16(17)23/h13-16,21-24H,3-12H2,1-2H3/t13-,14+,15-,16+,17-,18-,19-,20-/m0/s1","m_plus_h":"339.2530","m_plus_na":"361.2349","origin_reference":{"doi":"10.1039/p19730002841","pmid":null,"authors":"Dalziel, William; Hesp, Barrie; Stevenson, Karen M; Jarvis, John AJ","title":"The structure and absolute configuration of the antibiotic aphidicolin: a tetracyclic diterpenoid containing a new ring system","journal":"Journal of the Chemical Society, Perkin Transactions 1","year":1973,"volume":null,"issue":null,"pages":"2841-2851"},"origin_organism":{"id":30,"type":"Fungus","genus":"Cephalosporium","species":"aphidicola","taxon":{"id":964,"name":"Cephalosporium","rank":"genus","taxon_db":"mycobank","external_id":"7525","ncbi_id":81097,"ancestors":[{"id":599,"name":"Eukarya","rank":"domain","taxon_db":"mycobank","external_id":"0","ncbi_id":2759},{"id":600,"name":"Fungi","rank":"kingdom","taxon_db":"mycobank","external_id":"90157","ncbi_id":4751},{"id":617,"name":"Ascomycota","rank":"phylum","taxon_db":"mycobank","external_id":"90031","ncbi_id":4890},{"id":879,"name":"Sordariomycetes","rank":"class","taxon_db":"mycobank","external_id":"90350","ncbi_id":147550},{"id":899,"name":"Hypocreales","rank":"order","taxon_db":"mycobank","external_id":"90477","ncbi_id":5125}]}},"syntheses":["10.1021/ol034027+"],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.1039/p19730002841","structure_smiles":"C[C@]12CC[C@H]([C@@]([C@@H]1CC[C@@H]3[C@@]24CC[C@@]([C@H](C3)C4)(CO)O)(C)CO)O","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"mibig","external_db_code":"BGC0000676"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004695632%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00000081679%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00000081680%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004695630%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004695633%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004695634%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004695635%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004695636%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004695637%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004695638%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004695639%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004695640%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004695641%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004695642%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004695643%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00004695644%3%Aphidicolin"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00010114485%aphidicolin 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the five-carbon-unit precursors isopentenyl diphosphate and dimethylallyl diphosphate."},"smiles":"C[C@@]1(CO)[C@H](O)CC[C@@]2(C)[C@H]1CC[C@H]1C[C@@H]3C[C@]21CC[C@]3(O)CO","kingdom":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000000","name":"Organic compounds","chemont_id":"CHEMONTID:0000000","description":"Compounds that contain at least one carbon atom, excluding isocyanide/cyanide and their non-hydrocarbyl derivatives, thiophosgene, carbon diselenide, carbon monosulfide, carbon disulfide, carbon subsulfide, carbon monoxide, carbon dioxide, Carbon suboxide, and dicarbon monoxide."},"inchikey":"InChIKey=NOFOAYPPHIUXJR-APNQCZIXSA-N","subclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0001551","name":"Diterpenoids","chemont_id":"CHEMONTID:0001551","description":"Terpene compounds formed by four isoprene units."},"ancestors":["Alcohols and polyols","Aphidicolane and stemodane diterpenoids","Chemical entities","Cyclic alcohols and 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