{"id":10377,"npaid":"NPA010377","original_name":"Syringolin A","mol_formula":"C24H39N5O6","mol_weight":"493.6050","exact_mass":"493.2900","inchikey":"RUWSLQOIGKYPEZ-YPXRAQKDSA-N","smiles":"CC(C)[C@H](NC(=O)N[C@H](C(=O)N[C@H]1/C=C/CCNC(=O)/C=C/[C@H](C(C)C)NC1=O)C(C)C)C(=O)O","cluster_id":107,"node_id":102,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C24H39N5O6/c1-13(2)16-10-11-18(30)25-12-8-7-9-17(21(31)26-16)27-22(32)19(14(3)4)28-24(35)29-20(15(5)6)23(33)34/h7,9-11,13-17,19-20H,8,12H2,1-6H3,(H,25,30)(H,26,31)(H,27,32)(H,33,34)(H2,28,29,35)/b9-7+,11-10+/t16-,17+,19+,20+/m1/s1","m_plus_h":"494.2973","m_plus_na":"516.2792","origin_reference":{"doi":"10.1094/mpmi.1998.11.8.727","pmid":null,"authors":"Wäspi, Urs; Blanc, Daniel; Winkler, Tammo; Rüedi, Peter; Dudler, Robert","title":"Syringolin, a Novel Peptide Elicitor from Pseudomonas syringaepv.syringae that Induces Resistance toPyricularia oryzaein Rice","journal":"Molecular Plant-Microbe Interactions","year":1998,"volume":"11","issue":"8","pages":"727-733"},"origin_organism":{"id":4068,"type":"Bacterium","genus":"Pseudomonas","species":"syringaepv.syringae","taxon":{"id":86,"name":"Pseudomonas","rank":"genus","taxon_db":"lpsn","external_id":"517405","ncbi_id":286,"ancestors":[{"id":1,"name":"Bacteria","rank":"domain","taxon_db":"lpsn","external_id":"0","ncbi_id":2},{"id":2,"name":"Proteobacteria","rank":"phylum","taxon_db":"lpsn","external_id":"0","ncbi_id":1224},{"id":79,"name":"Gammaproteobacteria","rank":"class","taxon_db":"lpsn","external_id":"0","ncbi_id":1236},{"id":80,"name":"Pseudomonadales","rank":"order","taxon_db":"lpsn","external_id":"0","ncbi_id":72274},{"id":84,"name":"Pseudomonadaceae","rank":"family","taxon_db":"lpsn","external_id":"0","ncbi_id":135621}]}},"syntheses":["10.1021/ol100761z","10.1021/ol101252y","10.1002/anie.201402428"],"reassignments":[{"reference_doi":"10.1021/ol052039k","structure_smiles":"CC(C)[C@H](NC(=O)N[C@H](C(=O)N[C@H]1/C=C/CCNC(=O)/C=C/[C@H](C(C)C)NC1=O)C(C)C)C(=O)O"}],"mol_structures":[{"current_structure":false,"reference_doi":"10.1094/mpmi.1998.11.8.727","structure_smiles":"CC(C)C1/C=C\\C(=O)NCC/C=C\\C(C(=O)N1)NC(=O)C(C(C)C)NC(=O)NC(C(C)C)C(=O)O","is_reassignment":false,"version":1},{"current_structure":true,"reference_doi":"10.1021/ol052039k","structure_smiles":"CC(C)[C@H](NC(=O)N[C@H](C(=O)N[C@H]1/C=C/CCNC(=O)/C=C/[C@H](C(C)C)NC1=O)C(C)C)C(=O)O","is_reassignment":true,"version":2}],"exclusions":[],"external_ids":[{"external_db_name":"mibig","external_db_code":"BGC0000436"},{"external_db_name":"npmrd","external_db_code":"NP0185336"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000265","name":"Carboxylic 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