{"id":9301,"npaid":"NPA009301","original_name":"Brasiliamide D","mol_formula":"C24H28N2O5","mol_weight":"424.4970","exact_mass":"424.1998","inchikey":"LGVCEIBVKNARBM-BGERDNNASA-N","smiles":"CC(=O)N1C[C@@H](N(CC1CC2=CC3=C(C(=C2)OC)OCO3)C(=O)C)CC4=CC=CC=C4","cluster_id":3448,"node_id":2606,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C24H28N2O5/c1-16(27)25-14-21(10-19-11-22(29-3)24-23(12-19)30-15-31-24)26(17(2)28)13-20(25)9-18-7-5-4-6-8-18/h4-8,11-12,20-21H,9-10,13-15H2,1-3H3/t20-,21?/m0/s1","m_plus_h":"425.2071","m_plus_na":"447.1890","origin_reference":{"doi":"10.1271/bbb.68.820","pmid":15118309,"authors":"FUJITA, Tomoyuki; HAYASHI, Hideo","title":"New Brasiliamide Congeners, Brasiliamides C, D and E, from Penicillium brasilianum Batista JV-379","journal":"Bioscience Biotechnology and Biochemistry","year":2004,"volume":"68","issue":"4","pages":"820-826"},"origin_organism":{"id":3836,"type":"Fungus","genus":"Penicillium","species":"brasilianum Batista JV-379","taxon":{"id":1239,"name":"Penicillium","rank":"genus","taxon_db":"mycobank","external_id":"9257","ncbi_id":5073,"ancestors":[{"id":599,"name":"Eukarya","rank":"domain","taxon_db":"mycobank","external_id":"0","ncbi_id":2759},{"id":600,"name":"Fungi","rank":"kingdom","taxon_db":"mycobank","external_id":"90157","ncbi_id":4751},{"id":617,"name":"Ascomycota","rank":"phylum","taxon_db":"mycobank","external_id":"90031","ncbi_id":4890},{"id":1212,"name":"Eurotiomycetes","rank":"class","taxon_db":"mycobank","external_id":"501483","ncbi_id":147545},{"id":1235,"name":"Eurotiales","rank":"order","taxon_db":"mycobank","external_id":"90472","ncbi_id":5042},{"id":1236,"name":"Aspergillaceae","rank":"family","taxon_db":"mycobank","external_id":"80489","ncbi_id":1131492}]}},"syntheses":[],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.1271/bbb.68.820","structure_smiles":"CC(=O)N1C[C@@H](N(CC1CC2=CC3=C(C(=C2)OC)OCO3)C(=O)C)CC4=CC=CC=C4","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"mibig","external_db_code":"BGC0002278"},{"external_db_name":"gnps","external_db_code":"CCMSLIB00006675749%Brasiliamide D%3"},{"external_db_name":"npmrd","external_db_code":"NP0005314"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000296","name":"Benzodioxoles","chemont_id":"CHEMONTID:0000296","description":"Organic compounds containing a benzene ring fused to either isomers of dioxole. 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