{"id":7727,"npaid":"NPA007727","original_name":"Kendomycin","mol_formula":"C29H42O6","mol_weight":"486.6490","exact_mass":"486.2981","inchikey":"HKLDUJXJTQJSEJ-OLXNOMCWSA-N","smiles":"C[C@H]\\1CC[C@@H]2[C@@H]([C@@H]([C@H]([C@@H](O2)C3=C(C(=O)C(=C4C3=C[C@@](O4)([C@H](C[C@@H](C/C(=C1)/C)C)C)O)C)O)C)O)C","cluster_id":3418,"node_id":2583,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C29H42O6/c1-14-8-9-22-18(5)24(30)19(6)28(34-22)23-21-13-29(33,17(4)12-16(3)11-15(2)10-14)35-27(21)20(7)25(31)26(23)32/h10,13-14,16-19,22,24,28,30,32-33H,8-9,11-12H2,1-7H3/b15-10+/t14-,16+,17-,18-,19+,22+,24-,28+,29+/m0/s1","m_plus_h":"487.3054","m_plus_na":"509.2873","origin_reference":{"doi":"10.1039/a908387a","pmid":null,"authors":"Bode, Helge B; Zeeck, Axel","title":"Structure and biosynthesis of kendomycin, a carbocyclic ansa-compound from Streptomyces","journal":"Journal of the Chemical Society, Perkin Transactions 1","year":2000,"volume":null,"issue":"3","pages":"323-328"},"origin_organism":{"id":3493,"type":"Bacterium","genus":"Streptomyces","species":"violaceoruber","taxon":{"id":283,"name":"Streptomyces","rank":"genus","taxon_db":"lpsn","external_id":"517119","ncbi_id":1883,"ancestors":[{"id":1,"name":"Bacteria","rank":"domain","taxon_db":"lpsn","external_id":"0","ncbi_id":2},{"id":203,"name":"Actinobacteria","rank":"phylum","taxon_db":"lpsn","external_id":"0","ncbi_id":201174},{"id":204,"name":"Actinobacteria","rank":"class","taxon_db":"lpsn","external_id":"0","ncbi_id":null},{"id":275,"name":"Streptomycetales","rank":"order","taxon_db":"lpsn","external_id":"0","ncbi_id":85011},{"id":276,"name":"Streptomycetaceae","rank":"family","taxon_db":"lpsn","external_id":"0","ncbi_id":2062}]}},"syntheses":["10.1021/ja0447154","10.1021/ja051420x","10.1021/ol801499s","10.1002/anie.200900522","10.1021/ol100229f","10.1002/chem.201304580","10.1002/anie.201400305","10.1021/jo5015273"],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.1039/a908387a","structure_smiles":"C[C@H]\\1CC[C@@H]2[C@@H]([C@@H]([C@H]([C@@H](O2)C3=C(C(=O)C(=C4C3=C[C@@](O4)([C@H](C[C@@H](C/C(=C1)/C)C)C)O)C)O)C)O)C","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"mibig","external_db_code":"BGC0001066"},{"external_db_name":"npmrd","external_db_code":"NP0140717"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000301","name":"Benzofurans","chemont_id":"CHEMONTID:0000301","description":"Organic compounds containing a benzene ring fused to a furan. 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