{"id":7293,"npaid":"NPA007293","original_name":"Memnopeptide A","mol_formula":"C76H108N16O18S","mol_weight":"1565.8610","exact_mass":"1564.7748","inchikey":"GRBLBISGALXJDT-LHTGWLQBSA-N","smiles":"C[C@@H]1CC[C@@H]2[C@@]([C@@]13CC4=C(C=C5C(=C4O3)CN(C5=O)C(CCS(=O)C)C(=O)NC(CC6=CN=CN6)C(=O)NC(CCC(=O)N)C(=O)N7CCCC7C(=O)NC(CC8=CN=CN8)C(=O)NC(CCC(=O)N)C(=O)N9CCCC9C(=O)NC(CC(C)C)C(=O)N1CCCC1C(=O)N1CCCC1C(=O)O)O)(CC[C@H](C2(C)C)O)C","cluster_id":3268,"node_id":2484,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C76H108N16O18S/c1-40(2)30-51(71(105)90-27-10-14-55(90)72(106)91-28-11-15-56(91)73(107)108)87-66(100)53-13-9-26-89(53)70(104)48(18-21-61(78)96)83-63(97)49(31-42-35-79-38-81-42)85-65(99)52-12-8-25-88(52)69(103)47(17-20-60(77)95)84-64(98)50(32-43-36-80-39-82-43)86-67(101)54(23-29-111(7)109)92-37-46-44(68(92)102)33-57(93)45-34-76(110-62(45)46)41(3)16-19-58-74(4,5)59(94)22-24-75(58,76)6/h33,35-36,38-41,47-56,58-59,93-94H,8-32,34,37H2,1-7H3,(H2,77,95)(H2,78,96)(H,79,81)(H,80,82)(H,83,97)(H,84,98)(H,85,99)(H,86,101)(H,87,100)(H,107,108)/t41-,47?,48?,49?,50?,51?,52?,53?,54?,55?,56?,58+,59-,75+,76-,111?/m1/s1","m_plus_h":"1565.7821","m_plus_na":"1587.7640","origin_reference":{"doi":"10.7164/antibiotics.54.771","pmid":11776431,"authors":"Vertesy; Kogler; Markus; Schiell; Vogel; Wink","title":"Memnopeptide A, a novel terpene peptide from Memnoniella with an activating effect on SERCA2","journal":"Journal of Antibiotics","year":2001,"volume":"54","issue":"10","pages":"771-782"},"origin_organism":{"id":3379,"type":"Fungus","genus":"Memnoniella","species":"echinata FH 2272","taxon":{"id":974,"name":"Memnoniella","rank":"genus","taxon_db":"mycobank","external_id":"8900","ncbi_id":80382,"ancestors":[{"id":599,"name":"Eukarya","rank":"domain","taxon_db":"mycobank","external_id":"0","ncbi_id":2759},{"id":600,"name":"Fungi","rank":"kingdom","taxon_db":"mycobank","external_id":"90157","ncbi_id":4751},{"id":617,"name":"Ascomycota","rank":"phylum","taxon_db":"mycobank","external_id":"90031","ncbi_id":4890},{"id":879,"name":"Sordariomycetes","rank":"class","taxon_db":"mycobank","external_id":"90350","ncbi_id":147550},{"id":899,"name":"Hypocreales","rank":"order","taxon_db":"mycobank","external_id":"90477","ncbi_id":5125}]}},"syntheses":[],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.7164/antibiotics.54.771","structure_smiles":"C[C@@H]1CC[C@@H]2[C@@]([C@@]13CC4=C(C=C5C(=C4O3)CN(C5=O)C(CCS(=O)C)C(=O)NC(CC6=CN=CN6)C(=O)NC(CCC(=O)N)C(=O)N7CCCC7C(=O)NC(CC8=CN=CN8)C(=O)NC(CCC(=O)N)C(=O)N9CCCC9C(=O)NC(CC(C)C)C(=O)N1CCCC1C(=O)N1CCCC1C(=O)O)O)(CC[C@H](C2(C)C)O)C","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"npmrd","external_db_code":"NP0003961"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000265","name":"Carboxylic acids and derivatives","chemont_id":"CHEMONTID:0000265","description":"Compounds containing a carboxylic acid group with the formula -C(=O)OH or a derivative thereof."},"smiles":"[H]C(CCC(O)=N)(N=C(O)C([H])(CC1=CN=CN1)N=C(O)C([H])(CCS(C)=O)N1CC2=C3O[C@]4(CC3=C(O)C=C2C1=O)[C@]([H])(C)CC[C@@]1([H])C(C)(C)[C@]([H])(O)CC[C@]41C)C(=O)N1CCCC1([H])C(O)=NC([H])(CC1=CN=CN1)C(O)=NC([H])(CCC(O)=N)C(=O)N1CCCC1([H])C(O)=NC([H])(CC(C)C)C(=O)N1CCCC1([H])C(=O)N1CCCC1([H])C(O)=O","kingdom":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000000","name":"Organic compounds","chemont_id":"CHEMONTID:0000000","description":"Compounds that contain at least one carbon atom, excluding isocyanide/cyanide and their non-hydrocarbyl derivatives, thiophosgene, carbon diselenide, carbon monosulfide, carbon disulfide, carbon subsulfide, carbon monoxide, carbon dioxide, Carbon suboxide, and dicarbon monoxide."},"inchikey":"InChIKey=GRBLBISGALXJDT-LHTGWLQBSA-N","subclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000013","name":"Amino acids, peptides, and analogues","chemont_id":"CHEMONTID:0000013","description":"Organic compounds containing an amino acid or a peptide backbone, or derivatives thereof."},"ancestors":["1-hydroxy-2-unsubstituted benzenoids","Alcohols and polyols","Alkyl aryl ethers","Alpha amino acid amides","Alpha amino acids and derivatives","Amino acids and derivatives","Amino acids, peptides, and analogues","Azacyclic compounds","Azoles","Benzenoids","Carbonyl compounds","Carboximidic acids","Carboximidic acids and derivatives","Carboxylic acid amides","Carboxylic acid derivatives","Carboxylic acids","Carboxylic acids and derivatives","Chemical entities","Coumarans","Cyclic alcohols and derivatives","Ethers","Heteroaromatic compounds","Hydrocarbon derivatives","Imidazoles","Imidazolyl carboxylic acids and derivatives","Isoindoles","Isoindoles and derivatives","Isoindolines","Isoindolones","Lactams","Leucine and derivatives","Monocarboxylic acids and derivatives","N-acyl-alpha amino acids","N-acyl-alpha amino acids and derivatives","N-acylpyrrolidines","Oligopeptides","Organic 1,3-dipolar compounds","Organic acids and derivatives","Organic compounds","Organic nitrogen compounds","Organic oxides","Organic oxygen compounds","Organoheterocyclic compounds","Organonitrogen compounds","Organooxygen compounds","Organopnictogen compounds","Organosulfur compounds","Oxacyclic compounds","Peptides","Phenols","Proline and derivatives","Propargyl-type 1,3-dipolar organic compounds","Pyrrolidine carboxylic acids","Pyrrolidine carboxylic acids and derivatives","Pyrrolidinecarboxamides","Pyrrolidines","Secondary alcohols","Substituted imidazoles","Sulfinyl compounds","Sulfoxides","Tertiary carboxylic acid amides"],"superclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000264","name":"Organic acids and derivatives","chemont_id":"CHEMONTID:0000264","description":"Compounds an organic acid or a derivative thereof."},"description":"This compound belongs to the class of organic compounds known as oligopeptides. 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