{"id":7209,"npaid":"NPA007209","original_name":"Cystomanamide A","mol_formula":"C28H44N6O9","mol_weight":"608.6930","exact_mass":"608.3170","inchikey":"JENXRARIASYFRK-LXTLSNALSA-N","smiles":"CC(C)CCCCC[C@H](CC(=O)N[C@H](CC(=O)N)C(=O)N[C@@H]([C@H](C(=O)N)O)C(=O)N[C@H]([C@H](C1=CC=CC=C1)O)C(=O)O)N","cluster_id":2797,"node_id":2159,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C28H44N6O9/c1-15(2)9-5-3-8-12-17(29)13-20(36)32-18(14-19(30)35)26(40)33-21(24(38)25(31)39)27(41)34-22(28(42)43)23(37)16-10-6-4-7-11-16/h4,6-7,10-11,15,17-18,21-24,37-38H,3,5,8-9,12-14,29H2,1-2H3,(H2,30,35)(H2,31,39)(H,32,36)(H,33,40)(H,34,41)(H,42,43)/t17-,18-,21+,22-,23+,24-/m1/s1","m_plus_h":"609.3243","m_plus_na":"631.3062","origin_reference":{"doi":"10.1021/ol500779s","pmid":24735013,"authors":"Etzbach, Lena; Plaza, Alberto; Garcia, Ronald; Baumann, Sascha; Mueller, Rolf","title":"Cystomanamides: Structure and biosynthetic pathway of a family of glycosylated lipopeptides from myxobacteria","journal":"Organic Letters","year":2014,"volume":"16","issue":"9","pages":"2414-2417"},"origin_organism":{"id":2964,"type":"Bacterium","genus":"Cystobacter","species":"fuscus MCy9118","taxon":{"id":173,"name":"Cystobacter","rank":"genus","taxon_db":"lpsn","external_id":"515459","ncbi_id":42,"ancestors":[{"id":1,"name":"Bacteria","rank":"domain","taxon_db":"lpsn","external_id":"0","ncbi_id":2},{"id":2,"name":"Proteobacteria","rank":"phylum","taxon_db":"lpsn","external_id":"0","ncbi_id":1224},{"id":168,"name":"Deltaproteobacteria","rank":"class","taxon_db":"lpsn","external_id":"0","ncbi_id":28221},{"id":169,"name":"Myxococcales","rank":"order","taxon_db":"lpsn","external_id":"0","ncbi_id":29},{"id":170,"name":"Archangiaceae","rank":"family","taxon_db":"lpsn","external_id":"0","ncbi_id":39}]}},"syntheses":[],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.1021/ol500779s","structure_smiles":"CC(C)CCCCC[C@H](CC(=O)N[C@H](CC(=O)N)C(=O)N[C@@H]([C@H](C(=O)N)O)C(=O)N[C@H]([C@H](C1=CC=CC=C1)O)C(=O)O)N","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"mibig","external_db_code":"BGC0000335"},{"external_db_name":"npmrd","external_db_code":"NP0012728"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0001813","name":"Peptidomimetics","chemont_id":"CHEMONTID:0001813","description":"Compounds 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Monosaccharides have the general formula CnH2nOn."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0002279","name":"Benzene and substituted derivatives","chemont_id":"CHEMONTID:0002279","description":"Aromatic compounds containing one monocyclic ring system consisting of benzene."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0001663","name":"Secondary carboxylic acid amides","chemont_id":"CHEMONTID:0001663","description":"Compounds containing a secondary carboxylic acid amide functional group, with the general structure RC(=O)N(R')H (R,R'=alkyl, aryl)."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0001661","name":"Secondary alcohols","chemont_id":"CHEMONTID:0001661","description":"Compounds containing a secondary alcohol functional group, with the general structure HOC(R)(R') (R,R'=alkyl, aryl)."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0001662","name":"Primary carboxylic acid amides","chemont_id":"CHEMONTID:0001662","description":"Compounds comprising primary carboxylic acid amide functional group, with the general structure RC(=O)NH2."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0004176","name":"Amino acids","chemont_id":"CHEMONTID:0004176","description":"Organic compounds that contain at least one carboxyl group and one amino group."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0001137","name":"Monocarboxylic acids and derivatives","chemont_id":"CHEMONTID:0001137","description":"Carboxylic acids containing exactly one carboxyl groups."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0001205","name":"Carboxylic acids","chemont_id":"CHEMONTID:0001205","description":"Compounds containing a carboxylic acid group with the formula -C(=O)OH."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0004557","name":"Organopnictogen compounds","chemont_id":"CHEMONTID:0004557","description":"Compounds containing a bond between carbon a pnictogen atom. 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