{"id":5486,"npaid":"NPA005486","original_name":"Maniwamycin A","mol_formula":"C10H18N2O2","mol_weight":"198.2660","exact_mass":"198.1368","inchikey":"WFHYSKXBQMLHKH-VOQSLCQKSA-N","smiles":"CCCC/C=C/[N+]([O-])=N/[C@@H](C)C(C)=O","cluster_id":1875,"node_id":1510,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C10H18N2O2/c1-4-5-6-7-8-12(14)11-9(2)10(3)13/h7-9H,4-6H2,1-3H3/b8-7+,12-11-/t9-/m0/s1","m_plus_h":"199.1441","m_plus_na":"221.1260","origin_reference":{"doi":"10.7164/antibiotics.42.1535","pmid":2584134,"authors":"Nakayama; Takahashi; Itoh; Kamiya; Shiratsuchi; Otani","title":"Novel antifungal antibiotics maniwamycins A and B. I. Taxonomy of the producing organism, fermentation, isolation, physico-chemical properties and biological properties","journal":"Journal of Antibiotics","year":1989,"volume":"42","issue":"11","pages":"1535-1540"},"origin_organism":{"id":2058,"type":"Bacterium","genus":"Streptomyces","species":"prasinopilosus (KC-7367)","taxon":{"id":283,"name":"Streptomyces","rank":"genus","taxon_db":"lpsn","external_id":"517119","ncbi_id":1883,"ancestors":[{"id":1,"name":"Bacteria","rank":"domain","taxon_db":"lpsn","external_id":"0","ncbi_id":2},{"id":203,"name":"Actinobacteria","rank":"phylum","taxon_db":"lpsn","external_id":"0","ncbi_id":201174},{"id":204,"name":"Actinobacteria","rank":"class","taxon_db":"lpsn","external_id":"0","ncbi_id":null},{"id":275,"name":"Streptomycetales","rank":"order","taxon_db":"lpsn","external_id":"0","ncbi_id":85011},{"id":276,"name":"Streptomycetaceae","rank":"family","taxon_db":"lpsn","external_id":"0","ncbi_id":2062}]}},"syntheses":[],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.7164/antibiotics.42.1535","structure_smiles":"CCCC/C=C/[N+]([O-])=N/[C@@H](C)C(C)=O","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"npmrd","external_db_code":"NP0013949"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0003631","name":"Allyl-type 1,3-dipolar organic compounds","chemont_id":"CHEMONTID:0003631","description":"Organic 1,3-dipolar compounds with the general structure  X=Y+-Z- <-> X--Y+=Z<-> X+-Y-Z-<-> X-=Y-Z+ (X, Z = C, N, or O; Y = N or O)."},"smiles":"CCCC\\C=C\\[N+](\\[O-])=N\\[C@@H](C)C(C)=O","kingdom":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000000","name":"Organic compounds","chemont_id":"CHEMONTID:0000000","description":"Compounds that contain at least one carbon atom, excluding isocyanide/cyanide and their non-hydrocarbyl derivatives, thiophosgene, carbon diselenide, carbon monosulfide, carbon disulfide, carbon subsulfide, carbon monoxide, carbon dioxide, Carbon suboxide, and dicarbon monoxide."},"inchikey":"InChIKey=WFHYSKXBQMLHKH-VOQSLCQKSA-N","subclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0002037","name":"Azoxy compounds","chemont_id":"CHEMONTID:0002037","description":"Organic compounds sharing a common functional group with the general structure RN=N+(O-)R."},"ancestors":["Allyl-type 1,3-dipolar organic compounds","Azoxy compounds","Carbonyl compounds","Chemical entities","Hydrocarbon derivatives","Ketones","Organic 1,3-dipolar compounds","Organic compounds","Organic nitrogen compounds","Organic oxides","Organic oxygen compounds","Organic zwitterions","Organonitrogen compounds","Organooxygen compounds","Organopnictogen compounds"],"superclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0003630","name":"Organic 1,3-dipolar compounds","chemont_id":"CHEMONTID:0003630","description":"Electrically neutral organic molecules carrying a positive and a negative charge in one of their major canonical descriptions. 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Ketones that have one or more alpha-hydrogen atoms undergo keto-enol tautomerization, the tautomer being an enol."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0004557","name":"Organopnictogen compounds","chemont_id":"CHEMONTID:0004557","description":"Compounds containing a bond between carbon a pnictogen atom. Pnictogens are p-block element atoms that are in the group 15 of the periodic table."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000278","name":"Organonitrogen compounds","chemont_id":"CHEMONTID:0000278","description":"Organic compounds containing a nitrogen atom."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0003610","name":"Organic zwitterions","chemont_id":"CHEMONTID:0003610","description":"Organic neutral compounds having formal unit electrical charges of opposite sign."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0003940","name":"Organic oxides","chemont_id":"CHEMONTID:0003940","description":"Organic compounds containing an oxide group."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0004150","name":"Hydrocarbon derivatives","chemont_id":"CHEMONTID:0004150","description":"Derivatives of hydrocarbons obtained by substituting one or more carbon atoms by an heteroatom. 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