{"id":5470,"npaid":"NPA005470","original_name":"Tasiamide A","mol_formula":"C42H67N7O10","mol_weight":"830.0370","exact_mass":"829.4949","inchikey":"LNEYJLFOLWPLKO-WCJPLQDBSA-N","smiles":"CC[C@@H](C)[C@H](NC(=O)[C@@H](CCC(N)=O)N(C)C(=O)[C@H](CC(C)C)NC(=O)[C@@H](O)[C@@H](C)CC)C(=O)NCC(=O)N(C)[C@@H](CC1=CC=CC=C1)C(=O)N1CCC[C@@H]1C(=O)OC","cluster_id":613,"node_id":546,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C42H67N7O10/c1-10-26(5)35(46-37(53)30(19-20-33(43)50)48(8)40(56)29(22-25(3)4)45-39(55)36(52)27(6)11-2)38(54)44-24-34(51)47(7)32(23-28-16-13-12-14-17-28)41(57)49-21-15-18-31(49)42(58)59-9/h12-14,16-17,25-27,29-32,35-36,52H,10-11,15,18-24H2,1-9H3,(H2,43,50)(H,44,54)(H,45,55)(H,46,53)/t26-,27+,29+,30-,31-,32+,35+,36+/m1/s1","m_plus_h":"830.5022","m_plus_na":"852.4841","origin_reference":{"doi":"10.1021/np020184q","pmid":12350160,"authors":"Williams, Philip G.; Yoshida, Wesley Y.; Moore, Richard E.; Paul, Valerie J.","title":"Tasiamide, a cytotoxic peptide from the marine cyanobacterium Symploca sp","journal":"Journal of Natural Products","year":2002,"volume":"65","issue":"9","pages":"1336-1339"},"origin_organism":{"id":1515,"type":"Bacterium","genus":"Symploca","species":"sp.","taxon":{"id":488,"name":"Symploca","rank":"genus","taxon_db":"lpsn","external_id":"0","ncbi_id":105591,"ancestors":[{"id":1,"name":"Bacteria","rank":"domain","taxon_db":"lpsn","external_id":"0","ncbi_id":2},{"id":417,"name":"Cyanobacteria","rank":"phylum","taxon_db":"lpsn","external_id":"0","ncbi_id":1117},{"id":418,"name":"Cyanophyceae","rank":"class","taxon_db":"lpsn","external_id":"0","ncbi_id":null},{"id":473,"name":"Oscillatoriales","rank":"order","taxon_db":"lpsn","external_id":"0","ncbi_id":1150},{"id":486,"name":"Microcoleaceae","rank":"family","taxon_db":"lpsn","external_id":"0","ncbi_id":1892252}]}},"syntheses":["10.1002/psc.1051"],"reassignments":[{"reference_doi":"10.3390/md12042308","structure_smiles":"CC[C@@H](C)[C@H](NC(=O)[C@@H](CCC(N)=O)N(C)C(=O)[C@H](CC(C)C)NC(=O)[C@@H](O)[C@@H](C)CC)C(=O)NCC(=O)N(C)[C@@H](CC1=CC=CC=C1)C(=O)N1CCC[C@@H]1C(=O)OC"}],"mol_structures":[{"current_structure":false,"reference_doi":"10.1021/np020184q","structure_smiles":"CC[C@H](C)[C@@H](C(=O)NCC(=O)N(C)[C@H](CC1=CC=CC=C1)C(=O)N2CCC[C@H]2C(=O)OC)NC(=O)[C@H](CCC(=O)N)N(C)C(=O)[C@H](CC(C)C)NC(=O)[C@H]([C@@H](C)CC)O","is_reassignment":false,"version":1},{"current_structure":true,"reference_doi":"10.3390/md12042308","structure_smiles":"CC[C@@H](C)[C@H](NC(=O)[C@@H](CCC(N)=O)N(C)C(=O)[C@H](CC(C)C)NC(=O)[C@@H](O)[C@@H](C)CC)C(=O)NCC(=O)N(C)[C@@H](CC1=CC=CC=C1)C(=O)N1CCC[C@@H]1C(=O)OC","is_reassignment":true,"version":2}],"exclusions":[],"external_ids":[{"external_db_name":"npmrd","external_db_code":"NP0004348"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000265","name":"Carboxylic 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Monosaccharides have the general formula CnH2nOn."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0001664","name":"Tertiary carboxylic acid amides","chemont_id":"CHEMONTID:0001664","description":"Compounds containing an amide derivative of carboxylic acid, with the general structure RN(R1)C(R2)=O (R1-R2 any atom but H)."},{"url":"http://classyfire.wishartlab.com/tax_nodes/C0003416","name":"Methyl esters","chemont_id":"CHEMONTID:0003416","description":"Organic compounds containing a carboxyl group that is esterified with a methyl group. 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