{"id":5192,"npaid":"NPA005192","original_name":"Moenomycin H","mol_formula":"C43H66N5O34P","mol_weight":"1227.9760","exact_mass":"1227.3327","inchikey":"AYPBINFDHGMDSL-JHNAURKQSA-N","smiles":"CC1C([C@@H](C(C(O1)OC2[C@@H](C(C(OC2COC3C(C(C(C(O3)CO)O)O)O)OC4[C@H](C(C(OC4OP(=O)(O)OC[C@H](C(=O)O)O)C(=O)N)O)OC(=O)N)NC(=O)C)O)NC(=O)C)O)O[C@H]5C(C([C@H](C(O5)C(=O)NC6=C(CCC6=O)O)O)O)O","cluster_id":653,"node_id":579,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C43H66N5O34P/c1-9-29(76-41-27(62)24(59)25(60)33(79-41)36(65)48-17-12(52)4-5-13(17)53)21(56)18(46-10(2)50)38(73-9)77-30-16(8-71-40-26(61)23(58)20(55)15(6-49)74-40)75-39(19(22(30)57)47-11(3)51)80-34-31(81-43(45)68)28(63)32(35(44)64)78-42(34)82-83(69,70)72-7-14(54)37(66)67/h9,14-16,18-34,38-42,49,52,54-63H,4-8H2,1-3H3,(H2,44,64)(H2,45,68)(H,46,50)(H,47,51)(H,48,65)(H,66,67)(H,69,70)/t9?,14-,15?,16?,18?,19?,20?,21-,22-,23?,24?,25-,26?,27?,28?,29?,30?,31+,32?,33?,34?,38?,39?,40?,41-,42?/m1/s1","m_plus_h":"1228.3400","m_plus_na":"1250.3219","origin_reference":{"doi":"10.7164/antibiotics.22.597","pmid":4312665,"authors":"Schacht, U; Huber, G","title":"Moenomycin. VII. Isolation and properties of further components of the antibiotic moenomycin","journal":"Journal of Antibiotics","year":1969,"volume":"22","issue":"12","pages":"597"},"origin_organism":{"id":742,"type":"Bacterium","genus":"Streptomyces","species":"bambergiensis","taxon":{"id":283,"name":"Streptomyces","rank":"genus","taxon_db":"lpsn","external_id":"517119","ncbi_id":1883,"ancestors":[{"id":1,"name":"Bacteria","rank":"domain","taxon_db":"lpsn","external_id":"0","ncbi_id":2},{"id":203,"name":"Actinobacteria","rank":"phylum","taxon_db":"lpsn","external_id":"0","ncbi_id":201174},{"id":204,"name":"Actinobacteria","rank":"class","taxon_db":"lpsn","external_id":"0","ncbi_id":null},{"id":275,"name":"Streptomycetales","rank":"order","taxon_db":"lpsn","external_id":"0","ncbi_id":85011},{"id":276,"name":"Streptomycetaceae","rank":"family","taxon_db":"lpsn","external_id":"0","ncbi_id":2062}]}},"syntheses":[],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.7164/antibiotics.22.597","structure_smiles":"CC1C([C@@H](C(C(O1)OC2[C@@H](C(C(OC2COC3C(C(C(C(O3)CO)O)O)O)OC4[C@H](C(C(OC4OP(=O)(O)OC[C@H](C(=O)O)O)C(=O)N)O)OC(=O)N)NC(=O)C)O)NC(=O)C)O)O[C@H]5C(C([C@H](C(O5)C(=O)NC6=C(CCC6=O)O)O)O)O","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"npmrd","external_db_code":"NP0021371"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000323","name":"Organooxygen compounds","chemont_id":"CHEMONTID:0000323","description":"Organic compounds containing a bond between a carbon atom and an oxygen atom."},"smiles":"CC1OC(OC2[C@H](O)C(NC(C)=O)C(OC3C(OP(O)(=O)OC[C@@H](O)C(O)=O)OC(C(O)[C@@H]3OC(N)=O)C(N)=O)OC2COC2OC(CO)C(O)C(O)C2O)C(NC(C)=O)[C@@H](O)C1O[C@@H]1OC([C@H](O)C(O)C1O)C(=O)NC1=C(O)CCC1=O","kingdom":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000000","name":"Organic compounds","chemont_id":"CHEMONTID:0000000","description":"Compounds that contain at least one carbon atom, excluding isocyanide/cyanide and their non-hydrocarbyl derivatives, thiophosgene, carbon diselenide, carbon monosulfide, carbon disulfide, carbon subsulfide, carbon monoxide, carbon dioxide, Carbon suboxide, and dicarbon monoxide."},"inchikey":"InChIKey=AYPBINFDHGMDSL-JHNAURKQSA-N","subclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000011","name":"Carbohydrates and carbohydrate conjugates","chemont_id":"CHEMONTID:0000011","description":"Monosaccharides, disaccharides, oligosaccharides, polysaccharides, and their derivatives."},"ancestors":["Acetals","Acetamides","Alcohols and polyols","Alkyl phosphates","Alpha hydroxy acids and derivatives","Amino acids and derivatives","Amino acids, peptides, and analogues","Aminosaccharides","Carbamate esters","Carbamic acids and derivatives","Carbohydrates and carbohydrate conjugates","Carbonyl compounds","Carboxylic acid amides","Carboxylic acid derivatives","Carboxylic acids","Carboxylic acids and derivatives","Chemical entities","Cyclic ketones","Dialkyl phosphates","Ethers","Glycosyl compounds","Hydrocarbon derivatives","Hydroxy acids and derivatives","Ketones","Monocarboxylic acids and derivatives","N-acyl-alpha-hexosamines","O-glycosyl compounds","Oligosaccharides","Organic acids and derivatives","Organic carbonic acids and derivatives","Organic compounds","Organic nitrogen compounds","Organic oxides","Organic oxygen compounds","Organic phosphoric acids and derivatives","Organoheterocyclic compounds","Organonitrogen compounds","Organooxygen compounds","Organopnictogen compounds","Oxacyclic compounds","Oxanes","Phosphate esters","Polyols","Primary alcohols","Primary carboxylic acid amides","Pyrans","Secondary alcohols","Secondary carboxylic acid amides","Sugar acids and derivatives","Vinylogous acids"],"superclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0004603","name":"Organic oxygen compounds","chemont_id":"CHEMONTID:0004603","description":"Organic compounds that contain one or more oxygen atoms."},"description":"This compound belongs to the class of organic compounds known as oligosaccharides. 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