{"id":3313,"npaid":"NPA003313","original_name":"Michiganin A","mol_formula":"C92H145N25O26S4","mol_weight":"2145.5890","exact_mass":"2143.9675","inchikey":"MTKXZQFBKJNJJF-MJLJTCNBSA-N","smiles":"CC[C@H](C)[C@H]1C(=O)N[C@H](C(=O)N[C@H]2CSCC[C@@H](C(=O)N[C@H](C(=O)N[C@H](C(=O)N[C@H](C(=O)NCC(=O)N[C@@H](CCSC[C@H](NC(=O)[C@@H](NC2=O)C)C(=O)N[C@@H](CCCNC(=N)N)C(=O)O)C(=O)N1)CS)CCC(=O)O)[C@@H](C)CC)NC(=O)[C@H](CC(C)C)NC(=O)/C(=C/C)/NC(=O)[C@@H]3CSC[C@@H](C(=O)N[C@H](C(=O)NCC(=O)N[C@H](C(=O)N[C@H](C(=O)N3)CC(C)C)CC4=CNC5=CC=CC=C54)CO)NC(=O)[C@H](CO)N)[C@@H](C)CC","cluster_id":1858,"node_id":141,"has_exclusions":false,"synonyms":[],"inchi":"InChI=1S/C92H145N25O26S4/c1-13-45(9)70-88(139)105-54(23-24-69(122)123)78(129)110-62(38-144)76(127)99-34-67(120)101-55-25-28-145-40-64(86(137)106-57(91(142)143)22-19-27-96-92(94)95)111-73(124)48(12)100-84(135)63(114-89(140)71(46(10)14-2)117-90(141)72(47(11)15-3)116-79(55)130)39-146-29-26-56(80(131)115-70)104-81(132)58(30-43(5)6)107-77(128)52(16-4)103-85(136)66-42-147-41-65(112-74(125)51(93)36-118)87(138)109-61(37-119)75(126)98-35-68(121)102-60(32-49-33-97-53-21-18-17-20-50(49)53)83(134)108-59(31-44(7)8)82(133)113-66/h16-18,20-21,33,43-48,51,54-66,70-72,97,118-119,144H,13-15,19,22-32,34-42,93H2,1-12H3,(H,98,126)(H,99,127)(H,100,135)(H,101,120)(H,102,121)(H,103,136)(H,104,132)(H,105,139)(H,106,137)(H,107,128)(H,108,134)(H,109,138)(H,110,129)(H,111,124)(H,112,125)(H,113,133)(H,114,140)(H,115,131)(H,116,130)(H,117,141)(H,122,123)(H,142,143)(H4,94,95,96)/b52-16-/t45-,46-,47-,48-,51-,54-,55-,56-,57-,58-,59-,60-,61-,62-,63-,64-,65-,66-,70-,71-,72-/m0/s1","m_plus_h":"2144.9748","m_plus_na":"2166.9567","origin_reference":{"doi":"10.1128/aem.00639-06","pmid":16957199,"authors":"Holtsmark, I.; Mantzilas, D.; Eijsink, V. G. H.; Brurberg, M. B.","title":"Purification, Characterization, and Gene Sequence of Michiganin A, an Actagardine-Like Lantibiotic Produced by the Tomato Pathogen Clavibacter michiganensis subsp. michiganensis","journal":"Applied and Environmental Microbiology","year":2006,"volume":"72","issue":"9","pages":"5814-5821"},"origin_organism":{"id":2040,"type":"Bacterium","genus":"Clavibacter","species":"michiganensis","taxon":{"id":295,"name":"Clavibacter","rank":"genus","taxon_db":"lpsn","external_id":"515381","ncbi_id":1573,"ancestors":[{"id":1,"name":"Bacteria","rank":"domain","taxon_db":"lpsn","external_id":"0","ncbi_id":2},{"id":203,"name":"Actinobacteria","rank":"phylum","taxon_db":"lpsn","external_id":"0","ncbi_id":201174},{"id":204,"name":"Actinobacteria","rank":"class","taxon_db":"lpsn","external_id":"0","ncbi_id":null},{"id":285,"name":"Micrococcales","rank":"order","taxon_db":"lpsn","external_id":"0","ncbi_id":85006},{"id":294,"name":"Microbacteriaceae","rank":"family","taxon_db":"lpsn","external_id":"0","ncbi_id":85023}]}},"syntheses":[],"reassignments":[],"mol_structures":[{"current_structure":true,"reference_doi":"10.1128/aem.00639-06","structure_smiles":"CC[C@H](C)[C@H]1C(=O)N[C@H](C(=O)N[C@H]2CSCC[C@@H](C(=O)N[C@H](C(=O)N[C@H](C(=O)N[C@H](C(=O)NCC(=O)N[C@@H](CCSC[C@H](NC(=O)[C@@H](NC2=O)C)C(=O)N[C@@H](CCCNC(=N)N)C(=O)O)C(=O)N1)CS)CCC(=O)O)[C@@H](C)CC)NC(=O)[C@H](CC(C)C)NC(=O)/C(=C/C)/NC(=O)[C@@H]3CSC[C@@H](C(=O)N[C@H](C(=O)NCC(=O)N[C@H](C(=O)N[C@H](C(=O)N3)CC(C)C)CC4=CNC5=CC=CC=C54)CO)NC(=O)[C@H](CO)N)[C@@H](C)CC","is_reassignment":false,"version":1}],"exclusions":[],"external_ids":[{"external_db_name":"mibig","external_db_code":"BGC0000528"},{"external_db_name":"npmrd","external_db_code":"NP0006556"}],"classyfire":{"class":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0003298","name":"Polypeptides","chemont_id":"CHEMONTID:0003298","description":"Peptides containing ten or more amino acid residues."},"smiles":"CC[C@H](C)[C@@H]1NC(=O)[C@H](CCSC[C@@H]2NC(=O)[C@@H](NC(=O)[C@@H](NC(=O)[C@H](CCSC[C@H](NC(=O)[C@H](C)NC2=O)C(=O)N[C@@H](CCCNC(N)=N)C(O)=O)NC(=O)CNC(=O)[C@H](CS)NC(=O)[C@H](CCC(O)=O)NC1=O)[C@@H](C)CC)[C@@H](C)CC)NC(=O)[C@H](CC(C)C)NC(=O)C(\\NC(=O)[C@@H]1CSC[C@H](NC(=O)[C@@H](N)CO)C(=O)N[C@@H](CO)C(=O)NCC(=O)N[C@@H](Cc2c[nH]c3ccccc23)C(=O)N[C@@H](CC(C)C)C(=O)N1)=C\\C","kingdom":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0000000","name":"Organic compounds","chemont_id":"CHEMONTID:0000000","description":"Compounds that contain at least one carbon atom, excluding isocyanide/cyanide and their non-hydrocarbyl derivatives, thiophosgene, carbon diselenide, carbon monosulfide, carbon disulfide, carbon subsulfide, carbon monoxide, carbon dioxide, Carbon suboxide, and dicarbon monoxide."},"inchikey":"InChIKey=MTKXZQFBKJNJJF-MJLJTCNBSA-N","subclass":null,"ancestors":["3-alkylindoles","Alcohols and polyols","Alkylthiols","Alpha amino acid amides","Alpha amino acids and derivatives","Amines","Amino acids","Amino acids and derivatives","Amino acids, peptides, and analogues","Arginine and derivatives","Azacyclic compounds","Benzenoids","Carbonyl compounds","Carboximidamides","Carboxylic acid amides","Carboxylic acid derivatives","Carboxylic acids","Carboxylic acids and derivatives","Chemical entities","Cyclic peptides","Dialkylthioethers","Dicarboxylic acids and derivatives","Fatty Acyls","Fatty amides","Guanidines","Heteroaromatic compounds","Hydrocarbon derivatives","Imines","Indoles","Indoles and derivatives","Lactams","Leucine and derivatives","Lipids and lipid-like molecules","Macrolactams","Monoalkylamines","N-acyl amines","N-acyl-L-alpha-amino acids","N-acyl-alpha amino acids","N-acyl-alpha amino acids and derivatives","Organic Polymers","Organic acids and derivatives","Organic compounds","Organic nitrogen compounds","Organic oxides","Organic oxygen compounds","Organoheterocyclic compounds","Organonitrogen compounds","Organooxygen compounds","Organopnictogen compounds","Organosulfur compounds","Peptides","Phenylpropanoids and polyketides","Polypeptides","Primary alcohols","Primary amines","Pyrroles","Secondary carboxylic acid amides","Serine and derivatives","Substituted pyrroles","Thioethers","Thiols"],"superclass":{"url":"http://classyfire.wishartlab.com/tax_nodes/C0003297","name":"Organic Polymers","chemont_id":"CHEMONTID:0003297","description":"Organic compounds, generally large molecules or macromolecules, which are composed of many repeating units."},"description":"This compound belongs to the class of organic compounds known as polypeptides. 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